Positive charge distribution in (benzene)1(toleune)2                         + and (benzene)2(toluene)1                         + studied by photodissociation spectroscopy

Yoshiya Inokuchi; Kazuhiko Ohashi; Hiroshi Sekiya; Nobuyuki Nishi

doi:10.1063/1.1521126

Positive charge distribution in (benzene)₁(toleune)₂ ⁺ and (benzene)₂(toluene)₁ ⁺ studied by photodissociation spectroscopy

Yoshiya Inokuchi, Kazuhiko Ohashi, Hiroshi Sekiya, Nobuyuki Nishi

Physical Chemistry

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

The electronic and vibrational spectra of the benzene-toluene heterotrimer ions, B₁T₂ ⁺ and B₂T₁ ⁺, were observed using the tunable near-infrared and infrared lasers and the tandem mass spectrometer. The electronic spectra of both ions display the CR band, demonstrating that the positive charge is not localized on one molecule. The results were explained by the CR interaction between B₂ and T.

Original language	English
Pages (from-to)	10648-10653
Number of pages	6
Journal	Journal of Chemical Physics
Volume	117
Issue number	23
DOIs	https://doi.org/10.1063/1.1521126
Publication status	Published - Dec 15 2002

All Science Journal Classification (ASJC) codes

Physics and Astronomy(all)
Physical and Theoretical Chemistry

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10.1063/1.1521126

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Positive charge distribution in (benzene)₁(toleune)₂ ⁺ and (benzene)₂(toluene)₁ ⁺ studied by photodissociation spectroscopy. / Inokuchi, Yoshiya; Ohashi, Kazuhiko; Sekiya, Hiroshi et al.
In: Journal of Chemical Physics, Vol. 117, No. 23, 15.12.2002, p. 10648-10653.

Research output: Contribution to journal › Article › peer-review

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abstract = "The electronic and vibrational spectra of the benzene-toluene heterotrimer ions, B1T2 + and B2T1 +, were observed using the tunable near-infrared and infrared lasers and the tandem mass spectrometer. The electronic spectra of both ions display the CR band, demonstrating that the positive charge is not localized on one molecule. The results were explained by the CR interaction between B2 and T.",

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AU - Inokuchi, Yoshiya

AU - Ohashi, Kazuhiko

AU - Sekiya, Hiroshi

AU - Nishi, Nobuyuki

PY - 2002/12/15

Y1 - 2002/12/15

N2 - The electronic and vibrational spectra of the benzene-toluene heterotrimer ions, B1T2 + and B2T1 +, were observed using the tunable near-infrared and infrared lasers and the tandem mass spectrometer. The electronic spectra of both ions display the CR band, demonstrating that the positive charge is not localized on one molecule. The results were explained by the CR interaction between B2 and T.

AB - The electronic and vibrational spectra of the benzene-toluene heterotrimer ions, B1T2 + and B2T1 +, were observed using the tunable near-infrared and infrared lasers and the tandem mass spectrometer. The electronic spectra of both ions display the CR band, demonstrating that the positive charge is not localized on one molecule. The results were explained by the CR interaction between B2 and T.

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Positive charge distribution in (benzene)₁(toleune)₂ ⁺ and (benzene)₂(toluene)₁ ⁺ studied by photodissociation spectroscopy

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