Abstract
Here we report that the morphology of one-dimensional aggregates composed of porphyrins can be controlled by the peripheral hydrogen-bond donating/accepting groups and van der Waals interactions among alkyl chains introduced in the orthogonal axis toward the porphyrin-porphyrin π π stacking axis. The supramolecular assemblies of porphyrin derivatives were monitored by UV-Visible, XRD, SEM, TEM, and HR-TEM. Very interestingly, they afforded a variety of supramolecular morphologies such as helical ribbon, sphere, doughnut, and cylinder depending on the environmental conditions.
Original language | English |
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Pages | 4281-4282 |
Number of pages | 2 |
Publication status | Published - 2005 |
Event | 54th SPSJ Symposium on Macromolecules - Yamagata, Japan Duration: Sept 20 2005 → Sept 22 2005 |
Other
Other | 54th SPSJ Symposium on Macromolecules |
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Country/Territory | Japan |
City | Yamagata |
Period | 9/20/05 → 9/22/05 |
All Science Journal Classification (ASJC) codes
- Engineering(all)