POLYMERIZATION OF VINYL COMPOUNDS WITH HETEROCYCLIC GROUPS-4

C ASO C; T KUNITAKE T; M SHINSENJI M; H MIYAZAKI H

POLYMERIZATION OF VINYL COMPOUNDS WITH HETEROCYCLIC GROUPS-4

C ASO C, T KUNITAKE T, M SHINSENJI M, H MIYAZAKI H

Research output: Contribution to journal › Article › peer-review

Abstract

2-Vinylthiophene was found to undergo thermal polymerization; with benzene as diluent, overall rate of polymerization was proportional to 2. 5 power of monomer concentration, suggesting that thermal initiation is termolecular process; following Arrhenius equation was obtained from polymerization data for range 55 to 100 C; activation energy of thermal initiation was estimated to be 28. 2 kcal/mole, which was similar to those values obtained for styrene and 2-vinylfuran.

Original language	English
Pages (from-to)	1497-1508
Number of pages	12
Journal	J Polymer Science-Polymer Chem
Volume	7
Issue number	6 Pt A-1
Publication status	Published - 1969
Externally published	Yes

All Science Journal Classification (ASJC) codes

Engineering(all)

Cite this

@article{1b4836a04611432fb506fdb2f8cb2fce,

title = "POLYMERIZATION OF VINYL COMPOUNDS WITH HETEROCYCLIC GROUPS-4",

abstract = "2-Vinylthiophene was found to undergo thermal polymerization; with benzene as diluent, overall rate of polymerization was proportional to 2. 5 power of monomer concentration, suggesting that thermal initiation is termolecular process; following Arrhenius equation was obtained from polymerization data for range 55 to 100 C; activation energy of thermal initiation was estimated to be 28. 2 kcal/mole, which was similar to those values obtained for styrene and 2-vinylfuran.",

author = "{ASO C}, C and {KUNITAKE T}, T and {SHINSENJI M}, M and {MIYAZAKI H}, H",

year = "1969",

language = "English",

volume = "7",

pages = "1497--1508",

journal = "J Polymer Science-Polymer Chem",

number = "6 Pt A-1",

}

TY - JOUR

T1 - POLYMERIZATION OF VINYL COMPOUNDS WITH HETEROCYCLIC GROUPS-4

AU - ASO C, C

AU - KUNITAKE T, T

AU - SHINSENJI M, M

AU - MIYAZAKI H, H

PY - 1969

Y1 - 1969

N2 - 2-Vinylthiophene was found to undergo thermal polymerization; with benzene as diluent, overall rate of polymerization was proportional to 2. 5 power of monomer concentration, suggesting that thermal initiation is termolecular process; following Arrhenius equation was obtained from polymerization data for range 55 to 100 C; activation energy of thermal initiation was estimated to be 28. 2 kcal/mole, which was similar to those values obtained for styrene and 2-vinylfuran.

AB - 2-Vinylthiophene was found to undergo thermal polymerization; with benzene as diluent, overall rate of polymerization was proportional to 2. 5 power of monomer concentration, suggesting that thermal initiation is termolecular process; following Arrhenius equation was obtained from polymerization data for range 55 to 100 C; activation energy of thermal initiation was estimated to be 28. 2 kcal/mole, which was similar to those values obtained for styrene and 2-vinylfuran.

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UR - http://www.scopus.com/inward/citedby.url?scp=0014521809&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:0014521809

VL - 7

SP - 1497

EP - 1508

JO - J Polymer Science-Polymer Chem

JF - J Polymer Science-Polymer Chem

IS - 6 Pt A-1

ER -

POLYMERIZATION OF VINYL COMPOUNDS WITH HETEROCYCLIC GROUPS-4

Abstract

All Science Journal Classification (ASJC) codes

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