TY - JOUR
T1 - Platinum-catalyzed direct amination of allylic alcohols with aqueous ammonia
T2 - Selective synthesis of primary allylamines
AU - Das, Kalpataru
AU - Shibuya, Ryozo
AU - Nakahara, Yasuhito
AU - Germain, Nicolas
AU - Ohshima, Takashi
AU - Mashima, Kazushi
PY - 2012/1/2
Y1 - 2012/1/2
N2 - Direct amination of unactivated allylic alcohols with aqueous ammonia was catalyzed by a Pt/phosphine complex to give the corresponding allylamines along with water as the sole by-product. Under optimized reaction conditions, primary allylamines were obtained as major products with excellent monoallylation selectivity. cod=1,5-cyclooctadiene.
AB - Direct amination of unactivated allylic alcohols with aqueous ammonia was catalyzed by a Pt/phosphine complex to give the corresponding allylamines along with water as the sole by-product. Under optimized reaction conditions, primary allylamines were obtained as major products with excellent monoallylation selectivity. cod=1,5-cyclooctadiene.
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U2 - 10.1002/anie.201106737
DO - 10.1002/anie.201106737
M3 - Article
C2 - 22086866
AN - SCOPUS:84855283908
SN - 1433-7851
VL - 51
SP - 150
EP - 154
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
IS - 1
ER -