TY - JOUR
T1 - Photoelectron spectra of solvated electrons in bulk water, methanol, and ethanol
AU - Horio, Takuya
AU - Shen, Huan
AU - Adachi, Shunsuke
AU - Suzuki, Toshinori
N1 - Copyright:
Copyright 2012 Elsevier B.V., All rights reserved.
PY - 2012/5/11
Y1 - 2012/5/11
N2 - Photoelectron spectra of solvated electrons in bulk liquids were obtained at energy-resolution of 60 meV using a linear time-of-flight photoelectron spectrometer and a 100 kHz ultraviolet femtosecond laser. Solvated electrons in H 2O, D 2O, methanol, and ethanol were generated by 226 nm excitation of the charge-transfer-to-solvent bands of I - in 0.1 M NaI solutions, and the photoelectron spectra were measured using 260 nm pulses with a time delay of 2 ns. The electron binding energies and band shapes are discussed.
AB - Photoelectron spectra of solvated electrons in bulk liquids were obtained at energy-resolution of 60 meV using a linear time-of-flight photoelectron spectrometer and a 100 kHz ultraviolet femtosecond laser. Solvated electrons in H 2O, D 2O, methanol, and ethanol were generated by 226 nm excitation of the charge-transfer-to-solvent bands of I - in 0.1 M NaI solutions, and the photoelectron spectra were measured using 260 nm pulses with a time delay of 2 ns. The electron binding energies and band shapes are discussed.
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U2 - 10.1016/j.cplett.2012.03.051
DO - 10.1016/j.cplett.2012.03.051
M3 - Article
AN - SCOPUS:84860288389
SN - 0009-2614
VL - 535
SP - 12
EP - 16
JO - Chemical Physics Letters
JF - Chemical Physics Letters
ER -