Photodissociation of size-selected benzene cluster ions: (C6H6)n+ with n = 2-8

Yasuhiro Nakai; Kazuhiko Ohashi; Nobuyuki Nishi

doi:10.1021/j100199a009

Photodissociation of size-selected benzene cluster ions: (C₆H₆)_n⁺ with n = 2-8

Yasuhiro Nakai, Kazuhiko Ohashi, Nobuyuki Nishi

Physical Chemistry

Research output: Contribution to journal › Article › peer-review

12 Citations (Scopus)

Abstract

Photodissociation of size-selected benzene cluster ions, (C₆H₆)_n⁺ with n = 2-8, was investigated in the wavelength range of 440-960 nm. The average number of neutral monomers ejected from each cluster ion was obtained from the size distribution of photofragment ions. Two different electronic excitations (π ← π local excitation and charge resonance transition) exhibited a similar dissociation propensity with respect to the partitioning of the available energy. An upper bound of 0.35 ± 0.1 eV was determined for the average binding energy of a neutral monomer to a cluster ion with n = 6-8.

Original language	English
Pages (from-to)	7873-7876
Number of pages	4
Journal	Journal of physical chemistry
Volume	96
Issue number	20
DOIs	https://doi.org/10.1021/j100199a009
Publication status	Published - 1992

All Science Journal Classification (ASJC) codes

Engineering(all)
Physical and Theoretical Chemistry

Access to Document

10.1021/j100199a009

Cite this

@article{c54d52c8114141988d04891e4c8d421b,

title = "Photodissociation of size-selected benzene cluster ions: (C6H6)n+ with n = 2-8",

abstract = "Photodissociation of size-selected benzene cluster ions, (C6H6)n+ with n = 2-8, was investigated in the wavelength range of 440-960 nm. The average number of neutral monomers ejected from each cluster ion was obtained from the size distribution of photofragment ions. Two different electronic excitations (π ← π local excitation and charge resonance transition) exhibited a similar dissociation propensity with respect to the partitioning of the available energy. An upper bound of 0.35 ± 0.1 eV was determined for the average binding energy of a neutral monomer to a cluster ion with n = 6-8.",

author = "Yasuhiro Nakai and Kazuhiko Ohashi and Nobuyuki Nishi",

year = "1992",

doi = "10.1021/j100199a009",

language = "English",

volume = "96",

pages = "7873--7876",

journal = "Journal of physical chemistry",

issn = "0022-3654",

publisher = "American Chemical Society",

number = "20",

}

TY - JOUR

T1 - Photodissociation of size-selected benzene cluster ions

T2 - (C6H6)n+ with n = 2-8

AU - Nakai, Yasuhiro

AU - Ohashi, Kazuhiko

AU - Nishi, Nobuyuki

PY - 1992

Y1 - 1992

N2 - Photodissociation of size-selected benzene cluster ions, (C6H6)n+ with n = 2-8, was investigated in the wavelength range of 440-960 nm. The average number of neutral monomers ejected from each cluster ion was obtained from the size distribution of photofragment ions. Two different electronic excitations (π ← π local excitation and charge resonance transition) exhibited a similar dissociation propensity with respect to the partitioning of the available energy. An upper bound of 0.35 ± 0.1 eV was determined for the average binding energy of a neutral monomer to a cluster ion with n = 6-8.

AB - Photodissociation of size-selected benzene cluster ions, (C6H6)n+ with n = 2-8, was investigated in the wavelength range of 440-960 nm. The average number of neutral monomers ejected from each cluster ion was obtained from the size distribution of photofragment ions. Two different electronic excitations (π ← π local excitation and charge resonance transition) exhibited a similar dissociation propensity with respect to the partitioning of the available energy. An upper bound of 0.35 ± 0.1 eV was determined for the average binding energy of a neutral monomer to a cluster ion with n = 6-8.

UR - http://www.scopus.com/inward/record.url?scp=0000346560&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0000346560&partnerID=8YFLogxK

U2 - 10.1021/j100199a009

DO - 10.1021/j100199a009

M3 - Article

AN - SCOPUS:0000346560

SN - 0022-3654

VL - 96

SP - 7873

EP - 7876

JO - Journal of physical chemistry

JF - Journal of physical chemistry

IS - 20

ER -

Photodissociation of size-selected benzene cluster ions: (C₆H₆)_n⁺ with n = 2-8

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this