Photochemical reactions of palladium(0) and platinum(0) phosphine complexes

Taro Tsubomura; Ken Sakai

doi:10.1016/s0010-8545(98)90019-4

Photochemical reactions of palladium(0) and platinum(0) phosphine complexes

Taro Tsubomura, Ken Sakai

Research output: Contribution to journal › Article › peer-review

22 Citations (Scopus)

Abstract

Photochemical reactions of the binuclear palladium(0) complex [Pd₂(dppm)₃] with organic halides yield palladium(I) dihalogeno complexes with irradiation of visible light. Photooxidation of alcohols was observed for ethanol and 2-propanol with the palladium complex, Photophysical and quenching properties of a chiral [Pt(BINAP)₂] complex (BINAP = RR-or SS-2,2′-bis(diphenylphosphino)-1,1′-binaphthyl) were studied. The emitting MLCT excited state has a long lifetime. Photochemical reactions of [Pt(BINAP)₂] with organic halides cause halogen abstraction. Atom and electron transfer may be candidates for the initial stage of the photoreaction. The mechanism of the photoreaction is discussed with the quenching data.

Original language	English
Pages (from-to)	107-113
Number of pages	7
Journal	Coordination Chemistry Reviews
Volume	171
Issue number	1
DOIs	https://doi.org/10.1016/s0010-8545(98)90019-4
Publication status	Published - Apr 1998
Externally published	Yes

All Science Journal Classification (ASJC) codes

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/s0010-8545(98)90019-4

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title = "Photochemical reactions of palladium(0) and platinum(0) phosphine complexes",

abstract = "Photochemical reactions of the binuclear palladium(0) complex [Pd2(dppm)3] with organic halides yield palladium(I) dihalogeno complexes with irradiation of visible light. Photooxidation of alcohols was observed for ethanol and 2-propanol with the palladium complex, Photophysical and quenching properties of a chiral [Pt(BINAP)2] complex (BINAP = RR-or SS-2,2′-bis(diphenylphosphino)-1,1′-binaphthyl) were studied. The emitting MLCT excited state has a long lifetime. Photochemical reactions of [Pt(BINAP)2] with organic halides cause halogen abstraction. Atom and electron transfer may be candidates for the initial stage of the photoreaction. The mechanism of the photoreaction is discussed with the quenching data.",

author = "Taro Tsubomura and Ken Sakai",

year = "1998",

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doi = "10.1016/s0010-8545(98)90019-4",

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AU - Tsubomura, Taro

AU - Sakai, Ken

PY - 1998/4

Y1 - 1998/4

N2 - Photochemical reactions of the binuclear palladium(0) complex [Pd2(dppm)3] with organic halides yield palladium(I) dihalogeno complexes with irradiation of visible light. Photooxidation of alcohols was observed for ethanol and 2-propanol with the palladium complex, Photophysical and quenching properties of a chiral [Pt(BINAP)2] complex (BINAP = RR-or SS-2,2′-bis(diphenylphosphino)-1,1′-binaphthyl) were studied. The emitting MLCT excited state has a long lifetime. Photochemical reactions of [Pt(BINAP)2] with organic halides cause halogen abstraction. Atom and electron transfer may be candidates for the initial stage of the photoreaction. The mechanism of the photoreaction is discussed with the quenching data.

AB - Photochemical reactions of the binuclear palladium(0) complex [Pd2(dppm)3] with organic halides yield palladium(I) dihalogeno complexes with irradiation of visible light. Photooxidation of alcohols was observed for ethanol and 2-propanol with the palladium complex, Photophysical and quenching properties of a chiral [Pt(BINAP)2] complex (BINAP = RR-or SS-2,2′-bis(diphenylphosphino)-1,1′-binaphthyl) were studied. The emitting MLCT excited state has a long lifetime. Photochemical reactions of [Pt(BINAP)2] with organic halides cause halogen abstraction. Atom and electron transfer may be candidates for the initial stage of the photoreaction. The mechanism of the photoreaction is discussed with the quenching data.

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Photochemical reactions of palladium(0) and platinum(0) phosphine complexes

Abstract

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