Phenolate-bridged A2B-type subporphyrin dimer

Shoma Hirokawa, Shigeki Mori, Nagao Kobayashi, Soji Shimizu

Research output: Contribution to journalArticlepeer-review

2 Citations (Scopus)

Abstract

An ether cleavage reaction of A2B-type subporphyrin bearing an ortho-anisyl substituent afforded a phenolate-bridged dimer. A head-to-tail structure of the dimer was unambiguously elucidated by single crystal X-ray diffraction analysis. UV-vis absorption and magnetic circular dichroism spectra indicated a minor interaction between the subporphyrin chromophores. Density functional theory calculations provided a detailed insight into the electronic structures of the subporphyrin dimer.

Original languageEnglish
Pages (from-to)975-980
Number of pages6
JournalJournal of Porphyrins and Phthalocyanines
Volume25
Issue number10-12
DOIs
Publication statusPublished - Oct 1 2021

All Science Journal Classification (ASJC) codes

  • General Chemistry

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