Phase transformations in Pd- and Ni-rich Ti-Pd-Ni alloys

M. Nagasako, M. Nishida

Research output: Contribution to journalConference articlepeer-review

7 Citations (Scopus)


It has been found that Ti45Pd45Ni10 alloy shows peculiar phase transformations. Upon heating in DSC measurement, an endothermic reaction occurs firstly around 373 K, which corresponds to the reverse martensitic transformation from B19 to B2 structure. Subsequently, a pair of exothermic and endothermic peaks is observed from 550 to 740 K, which is due to the appearance and disappearance of new order phase with long period stacking structure. One of characteristic feature in electron diffraction pattern of the new phase is superlattice spots at 1/8 position in the row of reflections of 111B2*. Finally, an exothermic reaction which corresponds to the formation of Ti2(PdNi)3 phase is detected around 850 K. More interesting phenomenon, which is the parent phase stabilization with low temperature aging below 500 K, is discovered. The ω-like diffuse reflections with rather strong intensity are observed in electron diffraction patterns taken from the stabilized B2 phase. Morphological and crystallographic aspects of the new order phase are also discussed.

Original languageEnglish
Pages (from-to)1043-1046
Number of pages4
JournalJournal De Physique. IV : JP
Volume112 II
Publication statusPublished - Oct 2003
Externally publishedYes
EventInternational Conference on Martensitic Transformations - Espoo, Finland
Duration: Jun 10 2002Jun 14 2002

All Science Journal Classification (ASJC) codes

  • General Physics and Astronomy


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