Perfluorinated meso-aryl-substituted expanded porphyrins

Soji Shimizu; Ji Young Shin; Hiroyuki Furuta; Rami Ismael; Atsuhiro Osuka

doi:10.1002/anie.200390058

Perfluorinated meso-aryl-substituted expanded porphyrins

Soji Shimizu, Ji Young Shin, Hiroyuki Furuta, Rami Ismael, Atsuhiro Osuka

Research output: Contribution to journal › Article › peer-review

74 Citations (Scopus)

Abstract

Twisted figure-of-eight structures are found for the perfluorinated meso-aryl-substituted expanded porphyrins synthesized from 3,4-difluoropyrrole and pentafluorobenzaldehyde under modified Rothemund-Lindsey conditions. The crystal structure of the [26]hexaphyrin (see picture) consists of two almost planar tripyrrolic subunits which are tilted by approximately 60° in which a distinct alternation in the bond lengths of the π-electronic system is evident.

Original language	English
Pages (from-to)	78-82
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	42
Issue number	1
DOIs	https://doi.org/10.1002/anie.200390058
Publication status	Published - Jan 3 2003

All Science Journal Classification (ASJC) codes

Catalysis
Chemistry(all)

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AU - Furuta, Hiroyuki

AU - Ismael, Rami

AU - Osuka, Atsuhiro

PY - 2003/1/3

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AB - Twisted figure-of-eight structures are found for the perfluorinated meso-aryl-substituted expanded porphyrins synthesized from 3,4-difluoropyrrole and pentafluorobenzaldehyde under modified Rothemund-Lindsey conditions. The crystal structure of the [26]hexaphyrin (see picture) consists of two almost planar tripyrrolic subunits which are tilted by approximately 60° in which a distinct alternation in the bond lengths of the π-electronic system is evident.

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Perfluorinated meso-aryl-substituted expanded porphyrins

Abstract

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