TY - JOUR
T1 - Partial synthesis of a sea cucumber ganglioside analogue from a starfish cerebroside
AU - Higuchi, Ryuichi
AU - Mori, Takeshi
AU - Sugata, Tetsuji
AU - Yamada, Koji
AU - Miyamoto, Tomofumi
PY - 1999/1
Y1 - 1999/1
N2 - A sea cucumber ganglioside analogue 7 (NGNAα2→6Glcβ1→1Cer), which contains a phytosphingosine as a long-chain base and an α-hydroxy fatty acid, has been synthesized. Coupling of the methyl 2-thioglycoside derivative 5 of N-glycolylneuraminic acid with a cerebroside derivative 3, prepared from acanthacerebroside A (1), afforded protected ganglioside analogue 6, which was deprotected to give the corresponding ganglioside 7.
AB - A sea cucumber ganglioside analogue 7 (NGNAα2→6Glcβ1→1Cer), which contains a phytosphingosine as a long-chain base and an α-hydroxy fatty acid, has been synthesized. Coupling of the methyl 2-thioglycoside derivative 5 of N-glycolylneuraminic acid with a cerebroside derivative 3, prepared from acanthacerebroside A (1), afforded protected ganglioside analogue 6, which was deprotected to give the corresponding ganglioside 7.
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U2 - 10.1002/(sici)1099-0690(199901)1999:1<145::aid-ejoc145>3.0.co;2-e
DO - 10.1002/(sici)1099-0690(199901)1999:1<145::aid-ejoc145>3.0.co;2-e
M3 - Article
AN - SCOPUS:0032809168
SN - 1434-193X
SP - 145
EP - 147
JO - European Journal of Organic Chemistry
JF - European Journal of Organic Chemistry
IS - 1
ER -