Partial oxidation of alkenylsilanes with ozone: A novel stereoselective approach to the diol and triol derivatives

Kazunobu Igawa; Kyohei Sakita; Masanori Murakami; Katsuhiko Tomooka

doi:10.1055/s-2008-1032161

Partial oxidation of alkenylsilanes with ozone: A novel stereoselective approach to the diol and triol derivatives

Kazunobu Igawa, Kyohei Sakita, Masanori Murakami, Katsuhiko Tomooka

Department of Applied Molecular Chemistry

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

The reaction of alkenylsilanes with ozone provides synthetically versatile β-hydroxy or α-formyl silyl peroxides in good yield without normal fission of the C=C bond. The obtained α-formyl silyl peroxides serve as good precursors for the stereochemically defined diol or triol derivatives via nucleophilic addition to the formyl group and reduction of the peroxide moiety.

Original language	English
Article number	Z24207SS
Pages (from-to)	1641-1645
Number of pages	5
Journal	Synthesis
Issue number	10
DOIs	https://doi.org/10.1055/s-2008-1032161
Publication status	Published - May 19 2008

All Science Journal Classification (ASJC) codes

Catalysis
Organic Chemistry

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abstract = "The reaction of alkenylsilanes with ozone provides synthetically versatile β-hydroxy or α-formyl silyl peroxides in good yield without normal fission of the C=C bond. The obtained α-formyl silyl peroxides serve as good precursors for the stereochemically defined diol or triol derivatives via nucleophilic addition to the formyl group and reduction of the peroxide moiety.",

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AU - Sakita, Kyohei

AU - Murakami, Masanori

AU - Tomooka, Katsuhiko

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Partial oxidation of alkenylsilanes with ozone: A novel stereoselective approach to the diol and triol derivatives

Abstract

All Science Journal Classification (ASJC) codes

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