Palladium-catalyzed addition reaction of olefins, carbon tetrachloride and carbon monoxide in alcohols to give 2-alkyl-4,4,4-trichlorobutanoates

Jiro Tsuji; Koji Sato; Hideo Nagashima

doi:10.1016/S0040-4020(01)96745-6

Palladium-catalyzed addition reaction of olefins, carbon tetrachloride and carbon monoxide in alcohols to give 2-alkyl-4,4,4-trichlorobutanoates

Jiro Tsuji, Koji Sato, Hideo Nagashima

Research output: Contribution to journal › Article › peer-review

18 Citations (Scopus)

Abstract

Pd(OAc)₂ combined with PPh₃ is a good catalyst for the addition reaction of CCl₄ and CO to olefins in ethanol to afford ethyl 2-alkyl-4,4,4-trichlorobutanoates. The esters were obtained in satisfactory yields when the reaction was carried out at 50° in the presence of K₂CO₃ under CO pressure.

Original language	English
Pages (from-to)	5003-5006
Number of pages	4
Journal	Tetrahedron
Volume	41
Issue number	21
DOIs	https://doi.org/10.1016/S0040-4020(01)96745-6
Publication status	Published - 1985
Externally published	Yes

All Science Journal Classification (ASJC) codes

Biochemistry
Drug Discovery
Organic Chemistry

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title = "Palladium-catalyzed addition reaction of olefins, carbon tetrachloride and carbon monoxide in alcohols to give 2-alkyl-4,4,4-trichlorobutanoates",

abstract = "Pd(OAc)2 combined with PPh3 is a good catalyst for the addition reaction of CCl4 and CO to olefins in ethanol to afford ethyl 2-alkyl-4,4,4-trichlorobutanoates. The esters were obtained in satisfactory yields when the reaction was carried out at 50° in the presence of K2CO3 under CO pressure.",

author = "Jiro Tsuji and Koji Sato and Hideo Nagashima",

year = "1985",

doi = "10.1016/S0040-4020(01)96745-6",

language = "English",

volume = "41",

pages = "5003--5006",

journal = "Tetrahedron",

issn = "0040-4020",

publisher = "Elsevier Limited",

number = "21",

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T1 - Palladium-catalyzed addition reaction of olefins, carbon tetrachloride and carbon monoxide in alcohols to give 2-alkyl-4,4,4-trichlorobutanoates

AU - Tsuji, Jiro

AU - Sato, Koji

AU - Nagashima, Hideo

PY - 1985

Y1 - 1985

N2 - Pd(OAc)2 combined with PPh3 is a good catalyst for the addition reaction of CCl4 and CO to olefins in ethanol to afford ethyl 2-alkyl-4,4,4-trichlorobutanoates. The esters were obtained in satisfactory yields when the reaction was carried out at 50° in the presence of K2CO3 under CO pressure.

AB - Pd(OAc)2 combined with PPh3 is a good catalyst for the addition reaction of CCl4 and CO to olefins in ethanol to afford ethyl 2-alkyl-4,4,4-trichlorobutanoates. The esters were obtained in satisfactory yields when the reaction was carried out at 50° in the presence of K2CO3 under CO pressure.

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U2 - 10.1016/S0040-4020(01)96745-6

DO - 10.1016/S0040-4020(01)96745-6

M3 - Article

AN - SCOPUS:0039557465

SN - 0040-4020

VL - 41

SP - 5003

EP - 5006

JO - Tetrahedron

JF - Tetrahedron

IS - 21

ER -

Palladium-catalyzed addition reaction of olefins, carbon tetrachloride and carbon monoxide in alcohols to give 2-alkyl-4,4,4-trichlorobutanoates

Abstract

All Science Journal Classification (ASJC) codes

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