Oxygen evolution from water catalyzed by mononuclear ruthenium complexes with a triazamacrocyclic ligand in a facial fashion

Masaki Yoshida; Shigeyuki Masaoka; Ken Sakai

doi:10.1246/cl.2009.702

Oxygen evolution from water catalyzed by mononuclear ruthenium complexes with a triazamacrocyclic ligand in a facial fashion

Masaki Yoshida, Shigeyuki Masaoka, Ken Sakai

Inorganic and Analytical Chemistry

Research output: Contribution to journal › Article › peer-review

69 Citations (Scopus)

Abstract

[Ru(tmtacn)(R ₂bpy)(OH ₂)] ²⁺ (tmtacn=1,4,7-trimethyl-1,4,7-triazacyclononane; R ₂bpy=4,4'- disubstituted-2,2'-bipyridines, R=H, Me, and OMe) with tmtacn ligated in a facial fashion is found to be active as O ₂-evolving catalysts. It is also found that the stronger electron-donating character of R ₂bpy gives rise to the higher O ₂-evolving activity.

Original language	English
Pages (from-to)	702-703
Number of pages	2
Journal	Chemistry Letters
Volume	38
Issue number	7
DOIs	https://doi.org/10.1246/cl.2009.702
Publication status	Published - 2009

All Science Journal Classification (ASJC) codes

Chemistry(all)

Access to Document

10.1246/cl.2009.702

Cite this

@article{5a12b7e190464a0f865f6a6ae4183624,

title = "Oxygen evolution from water catalyzed by mononuclear ruthenium complexes with a triazamacrocyclic ligand in a facial fashion",

abstract = "[Ru(tmtacn)(R 2bpy)(OH 2)] 2+ (tmtacn=1,4,7-trimethyl-1,4,7-triazacyclononane; R 2bpy=4,4'- disubstituted-2,2'-bipyridines, R=H, Me, and OMe) with tmtacn ligated in a facial fashion is found to be active as O 2-evolving catalysts. It is also found that the stronger electron-donating character of R 2bpy gives rise to the higher O 2-evolving activity.",

author = "Masaki Yoshida and Shigeyuki Masaoka and Ken Sakai",

year = "2009",

doi = "10.1246/cl.2009.702",

language = "English",

volume = "38",

pages = "702--703",

journal = "Chemistry Letters",

issn = "0366-7022",

publisher = "The Chemical Society of Japan",

number = "7",

}

TY - JOUR

T1 - Oxygen evolution from water catalyzed by mononuclear ruthenium complexes with a triazamacrocyclic ligand in a facial fashion

AU - Yoshida, Masaki

AU - Masaoka, Shigeyuki

AU - Sakai, Ken

PY - 2009

Y1 - 2009

N2 - [Ru(tmtacn)(R 2bpy)(OH 2)] 2+ (tmtacn=1,4,7-trimethyl-1,4,7-triazacyclononane; R 2bpy=4,4'- disubstituted-2,2'-bipyridines, R=H, Me, and OMe) with tmtacn ligated in a facial fashion is found to be active as O 2-evolving catalysts. It is also found that the stronger electron-donating character of R 2bpy gives rise to the higher O 2-evolving activity.

AB - [Ru(tmtacn)(R 2bpy)(OH 2)] 2+ (tmtacn=1,4,7-trimethyl-1,4,7-triazacyclononane; R 2bpy=4,4'- disubstituted-2,2'-bipyridines, R=H, Me, and OMe) with tmtacn ligated in a facial fashion is found to be active as O 2-evolving catalysts. It is also found that the stronger electron-donating character of R 2bpy gives rise to the higher O 2-evolving activity.

UR - http://www.scopus.com/inward/record.url?scp=67650444674&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=67650444674&partnerID=8YFLogxK

U2 - 10.1246/cl.2009.702

DO - 10.1246/cl.2009.702

M3 - Article

AN - SCOPUS:67650444674

SN - 0366-7022

VL - 38

SP - 702

EP - 703

JO - Chemistry Letters

JF - Chemistry Letters

IS - 7

ER -

Oxygen evolution from water catalyzed by mononuclear ruthenium complexes with a triazamacrocyclic ligand in a facial fashion

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this