TY - JOUR
T1 - Oxidation of element 102, nobelium, with flow electrolytic column chromatography on an atom-at-a-time scale
AU - Toyoshima, Atsushi
AU - Kasamatsu, Yoshitaka
AU - Tsukada, Kazuaki
AU - Asai, Masato
AU - Kitatsuji, Yoshihiro
AU - Ishii, Yasuo
AU - Toume, Hayato
AU - Nishinaka, Ichiro
AU - Haba, Hiromitsu
AU - Ooe, Kazuhiro
AU - Sato, Wataru
AU - Shinohara, Atsushi
AU - Akiyama, Kazuhiko
AU - Nagame, Yuichiro
PY - 2009/7/8
Y1 - 2009/7/8
N2 - (Graph Presented) We report here on the successful oxidation of element 102, nobelium (No), on an atom-at-a-time scale in 0.1 M α- hydroxyisobutyric acid (α-HIB) solution using a newly developed technique, flow electrolytic column chromatography. It is found that the most stable ion, No2+, is oxidized to No3+ within 3 min and that the oxidized No complex with α-HIB holds the trivalent state in the column above an applied potential of 1.0 V.
AB - (Graph Presented) We report here on the successful oxidation of element 102, nobelium (No), on an atom-at-a-time scale in 0.1 M α- hydroxyisobutyric acid (α-HIB) solution using a newly developed technique, flow electrolytic column chromatography. It is found that the most stable ion, No2+, is oxidized to No3+ within 3 min and that the oxidized No complex with α-HIB holds the trivalent state in the column above an applied potential of 1.0 V.
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U2 - 10.1021/ja9030038
DO - 10.1021/ja9030038
M3 - Article
C2 - 19514720
AN - SCOPUS:67649973785
SN - 0002-7863
VL - 131
SP - 9180
EP - 9181
JO - Journal of the American Chemical Society
JF - Journal of the American Chemical Society
IS - 26
ER -