One-step synthesis of hyper-branched polymer with perfluoroalkyl segments

Masayuki Haraguchi; Tomoyasu Hirai; Masahiro Ozawa; Misao Miyamoto; Keiji Tanaka

One-step synthesis of hyper-branched polymer with perfluoroalkyl segments

Masayuki Haraguchi, Tomoyasu Hirai, Masahiro Ozawa, Misao Miyamoto, Keiji Tanaka

Research output: Contribution to journal › Article › peer-review

Abstract

Initiator-fragment incorporation radical polymerization (IFIRP) of commercially available fluorinated monomers was performed in the presence of cross-linking agents, resulting in a hyperbranched polymer with perfluoroalkyl groups (F-HBP). In our one-step method, a F-HBP was successfully prepared without gelation within 1 h. The FHBP exhibited interesting properties based on both the hyperbranched architecture and the perfluoroalkyl groups, such as good solubility in common organic solvents, high thermal stability, and low surface free energy.

Original language	English
Pages (from-to)	34-38
Number of pages	5
Journal	KGK Kautschuk Gummi Kunststoffe
Volume	65
Issue number	7-8
Publication status	Published - Jul 2012

All Science Journal Classification (ASJC) codes

Mechanical Engineering
Polymers and Plastics
Industrial and Manufacturing Engineering
Materials Chemistry

Cite this

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abstract = "Initiator-fragment incorporation radical polymerization (IFIRP) of commercially available fluorinated monomers was performed in the presence of cross-linking agents, resulting in a hyperbranched polymer with perfluoroalkyl groups (F-HBP). In our one-step method, a F-HBP was successfully prepared without gelation within 1 h. The FHBP exhibited interesting properties based on both the hyperbranched architecture and the perfluoroalkyl groups, such as good solubility in common organic solvents, high thermal stability, and low surface free energy.",

author = "Masayuki Haraguchi and Tomoyasu Hirai and Masahiro Ozawa and Misao Miyamoto and Keiji Tanaka",

year = "2012",

month = jul,

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T1 - One-step synthesis of hyper-branched polymer with perfluoroalkyl segments

AU - Haraguchi, Masayuki

AU - Hirai, Tomoyasu

AU - Ozawa, Masahiro

AU - Miyamoto, Misao

AU - Tanaka, Keiji

PY - 2012/7

Y1 - 2012/7

N2 - Initiator-fragment incorporation radical polymerization (IFIRP) of commercially available fluorinated monomers was performed in the presence of cross-linking agents, resulting in a hyperbranched polymer with perfluoroalkyl groups (F-HBP). In our one-step method, a F-HBP was successfully prepared without gelation within 1 h. The FHBP exhibited interesting properties based on both the hyperbranched architecture and the perfluoroalkyl groups, such as good solubility in common organic solvents, high thermal stability, and low surface free energy.

AB - Initiator-fragment incorporation radical polymerization (IFIRP) of commercially available fluorinated monomers was performed in the presence of cross-linking agents, resulting in a hyperbranched polymer with perfluoroalkyl groups (F-HBP). In our one-step method, a F-HBP was successfully prepared without gelation within 1 h. The FHBP exhibited interesting properties based on both the hyperbranched architecture and the perfluoroalkyl groups, such as good solubility in common organic solvents, high thermal stability, and low surface free energy.

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JF - KGK Kautschuk Gummi Kunststoffe

IS - 7-8

ER -

One-step synthesis of hyper-branched polymer with perfluoroalkyl segments

Abstract

All Science Journal Classification (ASJC) codes

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