One-pot aromatic bromination-rearrangement catalyzed by GaCl3

Mieko Arisawa; Atsushi Suwa; Masanori Ashikawa; Masahiko Yamaguchi

One-pot aromatic bromination-rearrangement catalyzed by GaCl₃

Mieko Arisawa, Atsushi Suwa, Masanori Ashikawa, Masahiko Yamaguchi

Research output: Contribution to journal › Article › peer-review

Abstract

Reaction of monoalkylbenzenes with bromine in the presence of a catalytic amount of GaCl₃ (5 mol %) initially gives o/p-bromination products, which are converted into mixtures containing considerable amounts of the m-brominated products. Notably, the bromination of dimethyl-, trimethyl-, and tetramethylbenzenes gives dibromo- and/or tribromoarenes, which are converted into monobromoarenes.

Original language	English
Pages (from-to)	24-34
Number of pages	11
Journal	Arkivoc
Volume	2003
Issue number	8
Publication status	Published - 2003
Externally published	Yes

All Science Journal Classification (ASJC) codes

Organic Chemistry

Cite this

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title = "One-pot aromatic bromination-rearrangement catalyzed by GaCl3",

abstract = "Reaction of monoalkylbenzenes with bromine in the presence of a catalytic amount of GaCl3 (5 mol %) initially gives o/p-bromination products, which are converted into mixtures containing considerable amounts of the m-brominated products. Notably, the bromination of dimethyl-, trimethyl-, and tetramethylbenzenes gives dibromo- and/or tribromoarenes, which are converted into monobromoarenes.",

author = "Mieko Arisawa and Atsushi Suwa and Masanori Ashikawa and Masahiko Yamaguchi",

year = "2003",

language = "English",

volume = "2003",

pages = "24--34",

journal = "Arkivoc",

issn = "1424-6376",

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T1 - One-pot aromatic bromination-rearrangement catalyzed by GaCl3

AU - Arisawa, Mieko

AU - Suwa, Atsushi

AU - Ashikawa, Masanori

AU - Yamaguchi, Masahiko

PY - 2003

Y1 - 2003

N2 - Reaction of monoalkylbenzenes with bromine in the presence of a catalytic amount of GaCl3 (5 mol %) initially gives o/p-bromination products, which are converted into mixtures containing considerable amounts of the m-brominated products. Notably, the bromination of dimethyl-, trimethyl-, and tetramethylbenzenes gives dibromo- and/or tribromoarenes, which are converted into monobromoarenes.

AB - Reaction of monoalkylbenzenes with bromine in the presence of a catalytic amount of GaCl3 (5 mol %) initially gives o/p-bromination products, which are converted into mixtures containing considerable amounts of the m-brominated products. Notably, the bromination of dimethyl-, trimethyl-, and tetramethylbenzenes gives dibromo- and/or tribromoarenes, which are converted into monobromoarenes.

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M3 - Article

AN - SCOPUS:3242708503

SN - 1424-6376

VL - 2003

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EP - 34

JO - Arkivoc

JF - Arkivoc

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ER -

One-pot aromatic bromination-rearrangement catalyzed by GaCl₃

Abstract

All Science Journal Classification (ASJC) codes

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