Nucleophilic substitution reaction at the nitrogen of arylsulfonamides with phosphide anion

Suguru Yoshida; Kazunobu Igawa; Katsuhiko Tomooka

doi:10.1021/ja309642r

Nucleophilic substitution reaction at the nitrogen of arylsulfonamides with phosphide anion

Suguru Yoshida, Kazunobu Igawa, Katsuhiko Tomooka

Department of Applied Molecular Chemistry

Research output: Contribution to journal › Article › peer-review

39 Citations (Scopus)

Abstract

A novel nucleophilic substitution reaction at the nitrogen of arylsulfonamides by means of phosphide anions has been described. This reaction allows for the efficient transformation of arylsulfonamides into synthetically valuable phosphamides, amines, and a variety of protected amines.

Original language	English
Pages (from-to)	19358-19361
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	134
Issue number	47
DOIs	https://doi.org/10.1021/ja309642r
Publication status	Published - Nov 28 2012

All Science Journal Classification (ASJC) codes

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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abstract = "A novel nucleophilic substitution reaction at the nitrogen of arylsulfonamides by means of phosphide anions has been described. This reaction allows for the efficient transformation of arylsulfonamides into synthetically valuable phosphamides, amines, and a variety of protected amines.",

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N2 - A novel nucleophilic substitution reaction at the nitrogen of arylsulfonamides by means of phosphide anions has been described. This reaction allows for the efficient transformation of arylsulfonamides into synthetically valuable phosphamides, amines, and a variety of protected amines.

AB - A novel nucleophilic substitution reaction at the nitrogen of arylsulfonamides by means of phosphide anions has been described. This reaction allows for the efficient transformation of arylsulfonamides into synthetically valuable phosphamides, amines, and a variety of protected amines.

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Nucleophilic substitution reaction at the nitrogen of arylsulfonamides with phosphide anion

Abstract

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