Nickel and palladium complexes of seco-tribenzoporphyrazines derived from one-pot condensation of 1,3-diiminoisoindoline

Ippei Sugita; Soji Shimizu; Takamitsu Fukuda; Nagao Kobayashi

doi:10.1016/j.tetlet.2013.01.057

Nickel and palladium complexes of seco-tribenzoporphyrazines derived from one-pot condensation of 1,3-diiminoisoindoline

Ippei Sugita, Soji Shimizu, Takamitsu Fukuda, Nagao Kobayashi

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

Unexpected formation of seco-tribenzoporphyrazines from nickel- or palladium-template macrocyclization reaction of 1,3-diiminoisoindoline as a sole starting material has opened a novel access to this class of molecules. Seco-tribenzoporphyrazines exhibit strongly-split Q band absorption, basically typical of tetraazachlorin-like electronic structures, which are discussed in detail based on UV-Vis absorption and magnetic circular dichroism spectroscopies and theoretical calculations.

Original language	English
Pages (from-to)	1599-1601
Number of pages	3
Journal	Tetrahedron Letters
Volume	54
Issue number	12
DOIs	https://doi.org/10.1016/j.tetlet.2013.01.057
Publication status	Published - Mar 20 2013
Externally published	Yes

All Science Journal Classification (ASJC) codes

Biochemistry
Drug Discovery
Organic Chemistry

Access to Document

10.1016/j.tetlet.2013.01.057

Cite this

@article{cb3ec0fcb0ad4d1b860f1d7ccf1d9559,

title = "Nickel and palladium complexes of seco-tribenzoporphyrazines derived from one-pot condensation of 1,3-diiminoisoindoline",

abstract = "Unexpected formation of seco-tribenzoporphyrazines from nickel- or palladium-template macrocyclization reaction of 1,3-diiminoisoindoline as a sole starting material has opened a novel access to this class of molecules. Seco-tribenzoporphyrazines exhibit strongly-split Q band absorption, basically typical of tetraazachlorin-like electronic structures, which are discussed in detail based on UV-Vis absorption and magnetic circular dichroism spectroscopies and theoretical calculations.",

author = "Ippei Sugita and Soji Shimizu and Takamitsu Fukuda and Nagao Kobayashi",

year = "2013",

month = mar,

day = "20",

doi = "10.1016/j.tetlet.2013.01.057",

language = "English",

volume = "54",

pages = "1599--1601",

journal = "Tetrahedron Letters",

issn = "0040-4039",

publisher = "Elsevier Limited",

number = "12",

}

TY - JOUR

T1 - Nickel and palladium complexes of seco-tribenzoporphyrazines derived from one-pot condensation of 1,3-diiminoisoindoline

AU - Sugita, Ippei

AU - Shimizu, Soji

AU - Fukuda, Takamitsu

AU - Kobayashi, Nagao

PY - 2013/3/20

Y1 - 2013/3/20

N2 - Unexpected formation of seco-tribenzoporphyrazines from nickel- or palladium-template macrocyclization reaction of 1,3-diiminoisoindoline as a sole starting material has opened a novel access to this class of molecules. Seco-tribenzoporphyrazines exhibit strongly-split Q band absorption, basically typical of tetraazachlorin-like electronic structures, which are discussed in detail based on UV-Vis absorption and magnetic circular dichroism spectroscopies and theoretical calculations.

AB - Unexpected formation of seco-tribenzoporphyrazines from nickel- or palladium-template macrocyclization reaction of 1,3-diiminoisoindoline as a sole starting material has opened a novel access to this class of molecules. Seco-tribenzoporphyrazines exhibit strongly-split Q band absorption, basically typical of tetraazachlorin-like electronic structures, which are discussed in detail based on UV-Vis absorption and magnetic circular dichroism spectroscopies and theoretical calculations.

UR - http://www.scopus.com/inward/record.url?scp=84873708629&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84873708629&partnerID=8YFLogxK

U2 - 10.1016/j.tetlet.2013.01.057

DO - 10.1016/j.tetlet.2013.01.057

M3 - Article

AN - SCOPUS:84873708629

SN - 0040-4039

VL - 54

SP - 1599

EP - 1601

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 12

ER -

Nickel and palladium complexes of seco-tribenzoporphyrazines derived from one-pot condensation of 1,3-diiminoisoindoline

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this