TY - JOUR
T1 - New iron(II) complexes for atom-transfer radical polymerization
T2 - The ligand design for triazacyclononane results in high reactivity and catalyst performance
AU - Kawamura, Mitsunobu
AU - Sunada, Yusuke
AU - Kai, Hidetomo
AU - Koike, Nobuyuki
AU - Hamada, Akane
AU - Hayakawa, Hitoshi
AU - Jin, Ren Hua
AU - Nagashima, Hideo
PY - 2009/9
Y1 - 2009/9
N2 - Mononuclear cordinatively unsaturated iron(II) complexes having a triazacyclononane ligand were developed as highly efficient and environmentally friendly catalysts for the atom-transfer radical polymerization (ATRP). These iron catalysts showed high performance in the well-controlled ATRP of styrene, methacrylates, and acrylates. The high reactivity of these catalysts led to well-controlled polymerization and block copolymerization even with lower catalyst concentrations.
AB - Mononuclear cordinatively unsaturated iron(II) complexes having a triazacyclononane ligand were developed as highly efficient and environmentally friendly catalysts for the atom-transfer radical polymerization (ATRP). These iron catalysts showed high performance in the well-controlled ATRP of styrene, methacrylates, and acrylates. The high reactivity of these catalysts led to well-controlled polymerization and block copolymerization even with lower catalyst concentrations.
UR - http://www.scopus.com/inward/record.url?scp=70349413084&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=70349413084&partnerID=8YFLogxK
U2 - 10.1002/adsc.200900216
DO - 10.1002/adsc.200900216
M3 - Article
AN - SCOPUS:70349413084
SN - 1615-4150
VL - 351
SP - 2086
EP - 2090
JO - Advanced Synthesis and Catalysis
JF - Advanced Synthesis and Catalysis
IS - 13
ER -