New alkaline earth aluminum hydride with one-dimensional zigzag chains of [AlH6]: Synthesis and crystal structure of BaAlH5

Qing An Zhang; Yumiko Nakamura; Ken ich Oikawa; Takashi Kamiyama; Etsuo Akiba

doi:10.1021/ic020388u

New alkaline earth aluminum hydride with one-dimensional zigzag chains of [AlH₆]: Synthesis and crystal structure of BaAlH₅

Qing An Zhang, Yumiko Nakamura, Ken ich Oikawa, Takashi Kamiyama, Etsuo Akiba

Research output: Contribution to journal › Article › peer-review

43 Citations (Scopus)

Abstract

The title hydride and its deuteride were successfully synthesized. The crystal structure of the deuteride was determined by time-of-flight neutron powder diffraction. BaAlD₅ crystallizes with a new orthorhombic structure in space group Pna2₁ (No. 33), cell parameters a = 9.194(1) Å, b = 7.0403(9) Å, and c = 5.1061(6) Å, Z = 4. BaAlH₅ is the first example that contains one-dimensional zigzag chains of [AlH₆] along the crystallographic c axis.

Original language	English
Pages (from-to)	6941-6943
Number of pages	3
Journal	Inorganic chemistry
Volume	41
Issue number	26
DOIs	https://doi.org/10.1021/ic020388u
Publication status	Published - Dec 30 2002
Externally published	Yes

All Science Journal Classification (ASJC) codes

Physical and Theoretical Chemistry
Inorganic Chemistry

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10.1021/ic020388u

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title = "New alkaline earth aluminum hydride with one-dimensional zigzag chains of [AlH6]: Synthesis and crystal structure of BaAlH5",

abstract = "The title hydride and its deuteride were successfully synthesized. The crystal structure of the deuteride was determined by time-of-flight neutron powder diffraction. BaAlD5 crystallizes with a new orthorhombic structure in space group Pna21 (No. 33), cell parameters a = 9.194(1) {\AA}, b = 7.0403(9) {\AA}, and c = 5.1061(6) {\AA}, Z = 4. BaAlH5 is the first example that contains one-dimensional zigzag chains of [AlH6] along the crystallographic c axis.",

author = "Zhang, {Qing An} and Yumiko Nakamura and Oikawa, {Ken ich} and Takashi Kamiyama and Etsuo Akiba",

year = "2002",

month = dec,

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doi = "10.1021/ic020388u",

language = "English",

volume = "41",

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journal = "Inorganic chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

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T1 - New alkaline earth aluminum hydride with one-dimensional zigzag chains of [AlH6]

T2 - Synthesis and crystal structure of BaAlH5

AU - Zhang, Qing An

AU - Nakamura, Yumiko

AU - Oikawa, Ken ich

AU - Kamiyama, Takashi

AU - Akiba, Etsuo

PY - 2002/12/30

Y1 - 2002/12/30

N2 - The title hydride and its deuteride were successfully synthesized. The crystal structure of the deuteride was determined by time-of-flight neutron powder diffraction. BaAlD5 crystallizes with a new orthorhombic structure in space group Pna21 (No. 33), cell parameters a = 9.194(1) Å, b = 7.0403(9) Å, and c = 5.1061(6) Å, Z = 4. BaAlH5 is the first example that contains one-dimensional zigzag chains of [AlH6] along the crystallographic c axis.

AB - The title hydride and its deuteride were successfully synthesized. The crystal structure of the deuteride was determined by time-of-flight neutron powder diffraction. BaAlD5 crystallizes with a new orthorhombic structure in space group Pna21 (No. 33), cell parameters a = 9.194(1) Å, b = 7.0403(9) Å, and c = 5.1061(6) Å, Z = 4. BaAlH5 is the first example that contains one-dimensional zigzag chains of [AlH6] along the crystallographic c axis.

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JO - Inorganic chemistry

JF - Inorganic chemistry

IS - 26

ER -

New alkaline earth aluminum hydride with one-dimensional zigzag chains of [AlH₆]: Synthesis and crystal structure of BaAlH₅

Abstract

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