New 3-D bimetallic magnetic compounds, [Ni(dipn)]3[M(CN) 6]2·7H2O (MIII = Fe, Co; dipn = N,N-di(3-aminopropyl)amine)

Masaaki Ohba; Mitsuteru Yamada; Naoki Usukp; Hisashi Ökawa

doi:10.1080/713738667

New 3-D bimetallic magnetic compounds, [Ni(dipn)]₃[M(CN) ₆]₂·7H₂O (M^III = Fe, Co; dipn = N,N-di(3-aminopropyl)amine)

Masaaki Ohba, Mitsuteru Yamada, Naoki Usukp, Hisashi Ökawa

Inorganic and Analytical Chemistry

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7 Citations (Scopus)

Abstract

New cyanide-bridged bimetallic compounds of the formula [Ni(dipn)] ₃[M(CN)₆]₂·7H₂O (M ^III = Fe (1), Co (2); dipn = N,N-di(3-aminopropyl)amine) were prepared and their crystal structures and magnetic properties were investigated. They are isostructural. In the crystal of 1 each [Fe(CN) makes bond to three [Ni(dipn)]^2- cations to form a 2-D sheet and the 2-D sheets are connected by [Ni(dipn)(H₂O)]^2- cations providing a 3-D network structure. 1 shows a ferromagnetic ordering in ihe bulk with T _C = 7.8 K.

Original language	English
Pages (from-to)	241-246
Number of pages	6
Journal	Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals
Volume	379
DOIs	https://doi.org/10.1080/713738667
Publication status	Published - 2002

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Condensed Matter Physics

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10.1080/713738667

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New 3-D bimetallic magnetic compounds, [Ni(dipn)]₃[M(CN) ₆]₂·7H₂O (M^III = Fe, Co; dipn = N,N-di(3-aminopropyl)amine). / Ohba, Masaaki; Yamada, Mitsuteru; Usukp, Naoki et al.
In: Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals, Vol. 379, 2002, p. 241-246.

Research output: Contribution to journal › Article › peer-review

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abstract = "New cyanide-bridged bimetallic compounds of the formula [Ni(dipn)] 3[M(CN)6]2·7H2O (M III = Fe (1), Co (2); dipn = N,N-di(3-aminopropyl)amine) were prepared and their crystal structures and magnetic properties were investigated. They are isostructural. In the crystal of 1 each [Fe(CN) makes bond to three [Ni(dipn)]2- cations to form a 2-D sheet and the 2-D sheets are connected by [Ni(dipn)(H2O)]2- cations providing a 3-D network structure. 1 shows a ferromagnetic ordering in ihe bulk with T C = 7.8 K.",

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AU - Yamada, Mitsuteru

AU - Usukp, Naoki

AU - Ökawa, Hisashi

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AB - New cyanide-bridged bimetallic compounds of the formula [Ni(dipn)] 3[M(CN)6]2·7H2O (M III = Fe (1), Co (2); dipn = N,N-di(3-aminopropyl)amine) were prepared and their crystal structures and magnetic properties were investigated. They are isostructural. In the crystal of 1 each [Fe(CN) makes bond to three [Ni(dipn)]2- cations to form a 2-D sheet and the 2-D sheets are connected by [Ni(dipn)(H2O)]2- cations providing a 3-D network structure. 1 shows a ferromagnetic ordering in ihe bulk with T C = 7.8 K.

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New 3-D bimetallic magnetic compounds, [Ni(dipn)]₃[M(CN) ₆]₂·7H₂O (M^III = Fe, Co; dipn = N,N-di(3-aminopropyl)amine)

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