N doping of oxide nanosheets

Yasumichi Matsumoto; Michio Koinuma; Yoshifumi Iwanaga; Tetsuya Sato; Shintaro Ida

doi:10.1021/ja807388t

N doping of oxide nanosheets

Yasumichi Matsumoto, Michio Koinuma, Yoshifumi Iwanaga, Tetsuya Sato, Shintaro Ida

Research output: Contribution to journal › Article › peer-review

72 Citations (Scopus)

Abstract

(Graph Presented) Photo-N doping for Nb-O system oxide nanosheets such as Nb₆O₁₇, TINbO₅, and Ca₂Nb ₃O₁₀ was succeeded in by treatment under mild conditions, where their H-restacked forms containing tetrabuthylammonium (TBA) ion were illuminated by UV light at room temperature. A relatively strong absorption in visible light region (400-600 nm) was observed for the N-doped samples because of formation of p-band or valence band hybridization of N in the Nb-O bandgap. The N doping proceeded only under TBA presence in water without O₂, and Pt loading promoted this doping reaction. It is proposed as a mechanism from the results of the doping for the Ti-O and Nb-O nanosheet mixed samples, that the Nb-O nanosheet acts as a photocatalyst for the N-doping reaction. This is the first report of N doping to oxide nanosheets.

Original language	English
Pages (from-to)	6644-6645
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	131
Issue number	19
DOIs	https://doi.org/10.1021/ja807388t
Publication status	Published - May 20 2009
Externally published	Yes

All Science Journal Classification (ASJC) codes

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

Access to Document

10.1021/ja807388t

Cite this

@article{9dfc32322a4349c499d66f1e5394dac1,

title = "N doping of oxide nanosheets",

abstract = "(Graph Presented) Photo-N doping for Nb-O system oxide nanosheets such as Nb6O17, TINbO5, and Ca2Nb 3O10 was succeeded in by treatment under mild conditions, where their H-restacked forms containing tetrabuthylammonium (TBA) ion were illuminated by UV light at room temperature. A relatively strong absorption in visible light region (400-600 nm) was observed for the N-doped samples because of formation of p-band or valence band hybridization of N in the Nb-O bandgap. The N doping proceeded only under TBA presence in water without O2, and Pt loading promoted this doping reaction. It is proposed as a mechanism from the results of the doping for the Ti-O and Nb-O nanosheet mixed samples, that the Nb-O nanosheet acts as a photocatalyst for the N-doping reaction. This is the first report of N doping to oxide nanosheets.",

author = "Yasumichi Matsumoto and Michio Koinuma and Yoshifumi Iwanaga and Tetsuya Sato and Shintaro Ida",

year = "2009",

month = may,

day = "20",

doi = "10.1021/ja807388t",

language = "English",

volume = "131",

pages = "6644--6645",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society",

number = "19",

}

TY - JOUR

T1 - N doping of oxide nanosheets

AU - Matsumoto, Yasumichi

AU - Koinuma, Michio

AU - Iwanaga, Yoshifumi

AU - Sato, Tetsuya

AU - Ida, Shintaro

PY - 2009/5/20

Y1 - 2009/5/20

N2 - (Graph Presented) Photo-N doping for Nb-O system oxide nanosheets such as Nb6O17, TINbO5, and Ca2Nb 3O10 was succeeded in by treatment under mild conditions, where their H-restacked forms containing tetrabuthylammonium (TBA) ion were illuminated by UV light at room temperature. A relatively strong absorption in visible light region (400-600 nm) was observed for the N-doped samples because of formation of p-band or valence band hybridization of N in the Nb-O bandgap. The N doping proceeded only under TBA presence in water without O2, and Pt loading promoted this doping reaction. It is proposed as a mechanism from the results of the doping for the Ti-O and Nb-O nanosheet mixed samples, that the Nb-O nanosheet acts as a photocatalyst for the N-doping reaction. This is the first report of N doping to oxide nanosheets.

AB - (Graph Presented) Photo-N doping for Nb-O system oxide nanosheets such as Nb6O17, TINbO5, and Ca2Nb 3O10 was succeeded in by treatment under mild conditions, where their H-restacked forms containing tetrabuthylammonium (TBA) ion were illuminated by UV light at room temperature. A relatively strong absorption in visible light region (400-600 nm) was observed for the N-doped samples because of formation of p-band or valence band hybridization of N in the Nb-O bandgap. The N doping proceeded only under TBA presence in water without O2, and Pt loading promoted this doping reaction. It is proposed as a mechanism from the results of the doping for the Ti-O and Nb-O nanosheet mixed samples, that the Nb-O nanosheet acts as a photocatalyst for the N-doping reaction. This is the first report of N doping to oxide nanosheets.

UR - http://www.scopus.com/inward/record.url?scp=67650526832&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=67650526832&partnerID=8YFLogxK

U2 - 10.1021/ja807388t

DO - 10.1021/ja807388t

M3 - Article

C2 - 19391623

AN - SCOPUS:67650526832

SN - 0002-7863

VL - 131

SP - 6644

EP - 6645

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 19

ER -

N doping of oxide nanosheets

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this