TY - JOUR
T1 - N -confused phlorin
T2 - A stable dihydroporphyrin isomer containing a confused pyrrole ring
AU - Ishida, Masatoshi
AU - Nakahara, Kensuke
AU - Sakashita, Ryuichi
AU - Ishizuka, Tomoya
AU - Watanabe, Motonori
AU - Uno, Hidemitsu
AU - Osuka, Atsuhiro
AU - Furuta, Hiroyuki
N1 - Funding Information:
The work in Kyushu was supported by the Grant-in-Aid for Scientific Research (No. 25248039 to HF) and Young Scientists (No. 26810024 to MI) from the Ministry of Education, Culture, Sports, Science and Technology of Japan.
Publisher Copyright:
© 2014 World Scientific Publishing Company.
PY - 2014/5/19
Y1 - 2014/5/19
N2 - Synthesis of bona fideN-confused phlorin derivatives through simple chemical reduction of N-confused porphyrin precursors using sodium borohydride, p-toluenesulfonyl hydrazide, etc. is described. Spectroscopic, X-ray diffraction analyses and DFT-assisted calculations of these species support the nonaromatic phlorin electronic structure.
AB - Synthesis of bona fideN-confused phlorin derivatives through simple chemical reduction of N-confused porphyrin precursors using sodium borohydride, p-toluenesulfonyl hydrazide, etc. is described. Spectroscopic, X-ray diffraction analyses and DFT-assisted calculations of these species support the nonaromatic phlorin electronic structure.
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U2 - 10.1142/S1088424614500692
DO - 10.1142/S1088424614500692
M3 - Article
AN - SCOPUS:84922780102
SN - 1088-4246
VL - 18
SP - 909
EP - 918
JO - Journal of Porphyrins and Phthalocyanines
JF - Journal of Porphyrins and Phthalocyanines
IS - 10-11
ER -