TY - JOUR
T1 - Multi-step spin crossover accompanied by symmetry breaking in an Fe III complex
T2 - Crystallographic evidence and DFT studies
AU - Li, Zhao Yang
AU - Dai, Jing Wei
AU - Shiota, Yoshihito
AU - Yoshizawa, Kazunari
AU - Kanegawa, Shinji
AU - Sato, Osamu
PY - 2013/9/23
Y1 - 2013/9/23
N2 - Spin doctor: A mononuclear ferric complex [Fe(H-5-Br-thsa)(5-Br-thsa)] ×H2O (1) (H2-5-Br-thsa=5-bromo-2-hydroxybenzylidene) hydrazinecarbothioamide) was synthesized and its magnetic properties and structure were investigated by DFT calculations. This complex shows unprecedented reversible, six/five-step spin-crossover behavior accompanied by symmetry breaking. More importantly, each step in the multi-step transition was successfully characterized by single-crystal X-ray diffraction.
AB - Spin doctor: A mononuclear ferric complex [Fe(H-5-Br-thsa)(5-Br-thsa)] ×H2O (1) (H2-5-Br-thsa=5-bromo-2-hydroxybenzylidene) hydrazinecarbothioamide) was synthesized and its magnetic properties and structure were investigated by DFT calculations. This complex shows unprecedented reversible, six/five-step spin-crossover behavior accompanied by symmetry breaking. More importantly, each step in the multi-step transition was successfully characterized by single-crystal X-ray diffraction.
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U2 - 10.1002/chem.201302272
DO - 10.1002/chem.201302272
M3 - Article
C2 - 24038606
AN - SCOPUS:84884533253
SN - 0947-6539
VL - 19
SP - 12948
EP - 12952
JO - Chemistry - A European Journal
JF - Chemistry - A European Journal
IS - 39
ER -