Monometallic and heterobimetallic azanickellacycles as ethylene polymerization catalysts

Masao Tanabiki; Kazuhiro Tsuchiya; Yukihiro Motoyama; Hideo Nagashima

doi:10.1039/b502942b

Monometallic and heterobimetallic azanickellacycles as ethylene polymerization catalysts

Masao Tanabiki, Kazuhiro Tsuchiya, Yukihiro Motoyama, Hideo Nagashima

Department of Applied Molecular Chemistry

Research output: Contribution to journal › Article › peer-review

38 Citations (Scopus)

Abstract

The azanickellacyclic complex (1) produced by trimerization of an isocyanide on the nickel atom is found to be a new ethylene polymerization catalyst; catalytic activity is increased by incorporation of the second metal to a diimino moiety of 1 leading to formation of heterobimetallic complexes.

Original language	English
Pages (from-to)	3409-3411
Number of pages	3
Journal	Chemical Communications
Issue number	27
DOIs	https://doi.org/10.1039/b502942b
Publication status	Published - Jul 21 2005

All Science Journal Classification (ASJC) codes

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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abstract = "The azanickellacyclic complex (1) produced by trimerization of an isocyanide on the nickel atom is found to be a new ethylene polymerization catalyst; catalytic activity is increased by incorporation of the second metal to a diimino moiety of 1 leading to formation of heterobimetallic complexes.",

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AU - Tanabiki, Masao

AU - Tsuchiya, Kazuhiro

AU - Motoyama, Yukihiro

AU - Nagashima, Hideo

PY - 2005/7/21

Y1 - 2005/7/21

N2 - The azanickellacyclic complex (1) produced by trimerization of an isocyanide on the nickel atom is found to be a new ethylene polymerization catalyst; catalytic activity is increased by incorporation of the second metal to a diimino moiety of 1 leading to formation of heterobimetallic complexes.

AB - The azanickellacyclic complex (1) produced by trimerization of an isocyanide on the nickel atom is found to be a new ethylene polymerization catalyst; catalytic activity is increased by incorporation of the second metal to a diimino moiety of 1 leading to formation of heterobimetallic complexes.

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DO - 10.1039/b502942b

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JO - Chemical Communications

JF - Chemical Communications

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Monometallic and heterobimetallic azanickellacycles as ethylene polymerization catalysts

Abstract

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