Molecular dispersion of chains in the mixed-valence complexes [M(en)2][MCl2(en)2] (M: Pt, Pd, Ni) and anionic amphiphiles in organic media

Nobuo Kimizuka, Sang Ho Lee, Toyoki Kunitake

    Research output: Contribution to journalArticlepeer-review

    57 Citations (Scopus)

    Abstract

    A way to prepare molecular electronic wires in organic media is the solubilization of one-dimensional mixed-valence complexes with varied metal species through the formation of amphiphilic supramolecular assemblies (see picture). Dissociation and reassembly of the complex was detected as thermochromism in the intervalence (M(II) → M(IV)) absorption bands.

    Original languageEnglish
    Pages (from-to)389-391
    Number of pages3
    JournalAngewandte Chemie - International Edition
    Volume39
    Issue number2
    DOIs
    Publication statusPublished - Jan 17 2000

    All Science Journal Classification (ASJC) codes

    • Catalysis
    • General Chemistry

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