Molecular aggregation structure of poly(fluoroalkyl acrylate) thin films evaluated by synchrotron-sourced grazing-incidence X-ray diffraction

Koji Honda; Hirohiko Yakabe; Tomoyuki Koga; Sono Sasaki; Osami Sakata; Hideyuki Otsuka; Atsushi Takahara

doi:10.1246/cl.2005.1024

Molecular aggregation structure of poly(fluoroalkyl acrylate) thin films evaluated by synchrotron-sourced grazing-incidence X-ray diffraction

Koji Honda, Hirohiko Yakabe, Tomoyuki Koga, Sono Sasaki, Osami Sakata, Hideyuki Otsuka, Atsushi Takahara

Department of Applied Molecular Chemistry

Research output: Contribution to journal › Article › peer-review

37 Citations (Scopus)

Abstract

Molecular aggregation structure of poly(fluoroalkyl acrylate) [PFA-C _y, where y is the fluoromethylene number of the fluoroalkyl (R _f) groups] thin films was characterized by grazing-incidence X-ray diffraction (GIXD). In-plane diffractions corresponding to the hexagonal packing of the R_f groups were measured for PFA-C_y with y ≥ 8 in the surface and bulk regions. This result indicated that the R_f groups were oriented almost perpendicular to the film surface.

Original language	English
Pages (from-to)	1024-1025
Number of pages	2
Journal	Chemistry Letters
Volume	34
Issue number	7
DOIs	https://doi.org/10.1246/cl.2005.1024
Publication status	Published - Jul 5 2005

All Science Journal Classification (ASJC) codes

Chemistry(all)

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10.1246/cl.2005.1024

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title = "Molecular aggregation structure of poly(fluoroalkyl acrylate) thin films evaluated by synchrotron-sourced grazing-incidence X-ray diffraction",

abstract = "Molecular aggregation structure of poly(fluoroalkyl acrylate) [PFA-C y, where y is the fluoromethylene number of the fluoroalkyl (R f) groups] thin films was characterized by grazing-incidence X-ray diffraction (GIXD). In-plane diffractions corresponding to the hexagonal packing of the Rf groups were measured for PFA-Cy with y ≥ 8 in the surface and bulk regions. This result indicated that the Rf groups were oriented almost perpendicular to the film surface.",

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AU - Honda, Koji

AU - Yakabe, Hirohiko

AU - Koga, Tomoyuki

AU - Sasaki, Sono

AU - Sakata, Osami

AU - Otsuka, Hideyuki

AU - Takahara, Atsushi

PY - 2005/7/5

Y1 - 2005/7/5

N2 - Molecular aggregation structure of poly(fluoroalkyl acrylate) [PFA-C y, where y is the fluoromethylene number of the fluoroalkyl (R f) groups] thin films was characterized by grazing-incidence X-ray diffraction (GIXD). In-plane diffractions corresponding to the hexagonal packing of the Rf groups were measured for PFA-Cy with y ≥ 8 in the surface and bulk regions. This result indicated that the Rf groups were oriented almost perpendicular to the film surface.

AB - Molecular aggregation structure of poly(fluoroalkyl acrylate) [PFA-C y, where y is the fluoromethylene number of the fluoroalkyl (R f) groups] thin films was characterized by grazing-incidence X-ray diffraction (GIXD). In-plane diffractions corresponding to the hexagonal packing of the Rf groups were measured for PFA-Cy with y ≥ 8 in the surface and bulk regions. This result indicated that the Rf groups were oriented almost perpendicular to the film surface.

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JF - Chemistry Letters

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Molecular aggregation structure of poly(fluoroalkyl acrylate) thin films evaluated by synchrotron-sourced grazing-incidence X-ray diffraction

Abstract

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