Metalation chemistry of meso-aryl-substituted expanded porphyrins

Soji Shimizu, Atsuhiro Osuka

Research output: Contribution to journalShort surveypeer-review

115 Citations (Scopus)


meso-Aryl-substituted expanded porphyrins are structural analogues of meso-aryl-substituted porphyrins. They exhibit rich and novel coordination behaviors, including multi-metal chelation due to the large cavities, spin-spin interaction arising from the proximity of metal centers, and large changes in their structural and electrochemical properties upon metalation. The recent discovery of a facile, one-pot synthesis of a series of meso-aryl-substituted expanded porphyrins enables us to investigate their metal-complexation chemistry. The aim of this Microreview is to highlight recent progress in the synthesis and characterization of metal complexes of meso-aryl-substituted expanded porphyrins.

Original languageEnglish
Pages (from-to)1319-1335
Number of pages17
JournalEuropean Journal of Inorganic Chemistry
Issue number7
Publication statusPublished - Apr 3 2006
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Inorganic Chemistry


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