mer-[Fe(pcq)(CN)3]-: A novel cyanide-containing building block and its application to assembling cyanide-bridged trinuclear FeIII2MnII complexes [pcq- = 8-(pyridine-2-carboxamido)quinoline anion]

Zhong Hai Ni; Hui Zhong Kou; Li Fang Zhang; Wei Wei Ni; Yun Bo Jiang; Ai Li Cui; Joan Ribas; Osamu Sato

doi:10.1021/ic051385v

mer-[Fe(pcq)(CN)₃]^-: A novel cyanide-containing building block and its application to assembling cyanide-bridged trinuclear Fe^III₂Mn^II complexes [pcq^- = 8-(pyridine-2-carboxamido)quinoline anion]

Zhong Hai Ni, Hui Zhong Kou, Li Fang Zhang, Wei Wei Ni, Yun Bo Jiang, Ai Li Cui, Joan Ribas, Osamu Sato

Department of Fundamental Organic Chemistry

Research output: Contribution to journal › Article › peer-review

70 Citations (Scopus)

Abstract

A new cyanide-containing building block K[Fe(pcq)(CN)₃] [1; pcq^- = 8-(pyridine-2-carboxamido)quinoline anion] containing a low-spin Fe^III center with three cyanide groups in a meridional arrangement has been successfully designed and synthesized. Three cyanide-bridged trinuclear Fe^III₂Mn^II complexes, [Fe(pcq)-(CN)₃]₂[Mn(CH₃OH) ₂(H₂O)₂]·2H₂O (2), [Fe(pcq)(CN)₃]₂[Mn(bipy)₂]· CH ₃OH·2H₂O (3), and [Fe(pcq)(CN)₃] ₂[Mn(phen)₂]·CH₃OH·2H ₂O (4), have been synthesized and structurally characterized. The magnetic susceptibilities of the three heterometallic complexes have been investigated.

Original language	English
Pages (from-to)	9631-9633
Number of pages	3
Journal	Inorganic chemistry
Volume	44
Issue number	26
DOIs	https://doi.org/10.1021/ic051385v
Publication status	Published - Dec 26 2005

All Science Journal Classification (ASJC) codes

Physical and Theoretical Chemistry
Inorganic Chemistry

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10.1021/ic051385v

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Ni, Z. H., Kou, H. Z., Zhang, L. F., Ni, W. W., Jiang, Y. B., Cui, A. L., Ribas, J., & Sato, O. (2005). mer-[Fe(pcq)(CN)₃]^-: A novel cyanide-containing building block and its application to assembling cyanide-bridged trinuclear Fe^III₂Mn^II complexes [pcq^- = 8-(pyridine-2-carboxamido)quinoline anion]. Inorganic chemistry, 44(26), 9631-9633. https://doi.org/10.1021/ic051385v

mer-[Fe(pcq)(CN)₃]^-: A novel cyanide-containing building block and its application to assembling cyanide-bridged trinuclear Fe^III₂Mn^II complexes [pcq^- = 8-(pyridine-2-carboxamido)quinoline anion]. / Ni, Zhong Hai; Kou, Hui Zhong; Zhang, Li Fang et al.
In: Inorganic chemistry, Vol. 44, No. 26, 26.12.2005, p. 9631-9633.

Research output: Contribution to journal › Article › peer-review

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title = "mer-[Fe(pcq)(CN)3]-: A novel cyanide-containing building block and its application to assembling cyanide-bridged trinuclear FeIII2MnII complexes [pcq- = 8-(pyridine-2-carboxamido)quinoline anion]",

abstract = "A new cyanide-containing building block K[Fe(pcq)(CN)3] [1; pcq- = 8-(pyridine-2-carboxamido)quinoline anion] containing a low-spin FeIII center with three cyanide groups in a meridional arrangement has been successfully designed and synthesized. Three cyanide-bridged trinuclear FeIII2MnII complexes, [Fe(pcq)-(CN)3]2[Mn(CH3OH) 2(H2O)2]·2H2O (2), [Fe(pcq)(CN)3]2[Mn(bipy)2]· CH 3OH·2H2O (3), and [Fe(pcq)(CN)3] 2[Mn(phen)2]·CH3OH·2H 2O (4), have been synthesized and structurally characterized. The magnetic susceptibilities of the three heterometallic complexes have been investigated.",

author = "Ni, {Zhong Hai} and Kou, {Hui Zhong} and Zhang, {Li Fang} and Ni, {Wei Wei} and Jiang, {Yun Bo} and Cui, {Ai Li} and Joan Ribas and Osamu Sato",

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doi = "10.1021/ic051385v",

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AU - Ni, Zhong Hai

AU - Kou, Hui Zhong

AU - Zhang, Li Fang

AU - Ni, Wei Wei

AU - Jiang, Yun Bo

AU - Cui, Ai Li

AU - Ribas, Joan

AU - Sato, Osamu

PY - 2005/12/26

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N2 - A new cyanide-containing building block K[Fe(pcq)(CN)3] [1; pcq- = 8-(pyridine-2-carboxamido)quinoline anion] containing a low-spin FeIII center with three cyanide groups in a meridional arrangement has been successfully designed and synthesized. Three cyanide-bridged trinuclear FeIII2MnII complexes, [Fe(pcq)-(CN)3]2[Mn(CH3OH) 2(H2O)2]·2H2O (2), [Fe(pcq)(CN)3]2[Mn(bipy)2]· CH 3OH·2H2O (3), and [Fe(pcq)(CN)3] 2[Mn(phen)2]·CH3OH·2H 2O (4), have been synthesized and structurally characterized. The magnetic susceptibilities of the three heterometallic complexes have been investigated.

AB - A new cyanide-containing building block K[Fe(pcq)(CN)3] [1; pcq- = 8-(pyridine-2-carboxamido)quinoline anion] containing a low-spin FeIII center with three cyanide groups in a meridional arrangement has been successfully designed and synthesized. Three cyanide-bridged trinuclear FeIII2MnII complexes, [Fe(pcq)-(CN)3]2[Mn(CH3OH) 2(H2O)2]·2H2O (2), [Fe(pcq)(CN)3]2[Mn(bipy)2]· CH 3OH·2H2O (3), and [Fe(pcq)(CN)3] 2[Mn(phen)2]·CH3OH·2H 2O (4), have been synthesized and structurally characterized. The magnetic susceptibilities of the three heterometallic complexes have been investigated.

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mer-[Fe(pcq)(CN)₃]^-: A novel cyanide-containing building block and its application to assembling cyanide-bridged trinuclear Fe^III₂Mn^II complexes [pcq^- = 8-(pyridine-2-carboxamido)quinoline anion]

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