Mechanistic study on reduction of nitric oxide to nitrous oxide using a dicopper complex

Yohei Kametani, Tsukasa Abe, Kazunari Yoshizawa, Yoshihito Shiota

Research output: Contribution to journalArticlepeer-review

1 Citation (Scopus)

Abstract

A density functional theory study was carried out to investigate the reduction mechanisms of NO to N2O using a dicopper complex reported by Zhang and coworkers (J. Am. Chem. Soc., 2019, 141, 10159-10164). The reaction mechanism consists of three steps: N-N bond formation, isomerization of the resultant N2O2 moiety, and cleavage of the N-O bond.

Original languageEnglish
Pages (from-to)5399-5403
Number of pages5
JournalDalton Transactions
Volume51
Issue number14
DOIs
Publication statusPublished - Mar 15 2022

All Science Journal Classification (ASJC) codes

  • Inorganic Chemistry

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