Measurement of the Md3+/Md2+ reduction potential studied with flow electrolytic chromatography

Atsushi Toyoshima; Zijie Li; Masato Asai; Nozomi Sato; Tetsuya K. Sato; Takahiro Kikuchi; Yusuke Kaneya; Yoshihiro Kitatsuji; Kazuaki Tsukada; Yuichiro Nagame; Matthias Schädel; Kazuhiro Ooe; Yoshitaka Kasamatsu; Atsushi Shinohara; Hiromitsu Haba; Julia Even

doi:10.1021/ic401571h

Measurement of the Md³⁺/Md²⁺ reduction potential studied with flow electrolytic chromatography

Atsushi Toyoshima, Zijie Li, Masato Asai, Nozomi Sato, Tetsuya K. Sato, Takahiro Kikuchi, Yusuke Kaneya, Yoshihiro Kitatsuji, Kazuaki Tsukada, Yuichiro Nagame, Matthias Schädel, Kazuhiro Ooe, Yoshitaka Kasamatsu, Atsushi Shinohara, Hiromitsu Haba, Julia Even

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

The reduction behavior of mendelevium (Md) was studied using a flow electrolytic chromatography apparatus. By application of the appropriate potentials on the chromatography column, the more stable Md³⁺ is reduced to Md²⁺. The reduction potential of the Md³⁺ + e^- → Md²⁺ couple was determined to be -0.16 ± 0.05 V versus a normal hydrogen electrode.

Original language	English
Pages (from-to)	12311-12313
Number of pages	3
Journal	Inorganic chemistry
Volume	52
Issue number	21
DOIs	https://doi.org/10.1021/ic401571h
Publication status	Published - Nov 4 2013
Externally published	Yes

All Science Journal Classification (ASJC) codes

Physical and Theoretical Chemistry
Inorganic Chemistry

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10.1021/ic401571h

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Toyoshima, A., Li, Z., Asai, M., Sato, N., Sato, T. K., Kikuchi, T., Kaneya, Y., Kitatsuji, Y., Tsukada, K., Nagame, Y., Schädel, M., Ooe, K., Kasamatsu, Y., Shinohara, A., Haba, H., & Even, J. (2013). Measurement of the Md³⁺/Md²⁺ reduction potential studied with flow electrolytic chromatography. Inorganic chemistry, 52(21), 12311-12313. https://doi.org/10.1021/ic401571h

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abstract = "The reduction behavior of mendelevium (Md) was studied using a flow electrolytic chromatography apparatus. By application of the appropriate potentials on the chromatography column, the more stable Md3+ is reduced to Md2+. The reduction potential of the Md3+ + e- → Md2+ couple was determined to be -0.16 ± 0.05 V versus a normal hydrogen electrode.",

author = "Atsushi Toyoshima and Zijie Li and Masato Asai and Nozomi Sato and Sato, {Tetsuya K.} and Takahiro Kikuchi and Yusuke Kaneya and Yoshihiro Kitatsuji and Kazuaki Tsukada and Yuichiro Nagame and Matthias Sch{\"a}del and Kazuhiro Ooe and Yoshitaka Kasamatsu and Atsushi Shinohara and Hiromitsu Haba and Julia Even",

year = "2013",

month = nov,

day = "4",

doi = "10.1021/ic401571h",

language = "English",

volume = "52",

pages = "12311--12313",

journal = "Inorganic chemistry",

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T1 - Measurement of the Md3+/Md2+ reduction potential studied with flow electrolytic chromatography

AU - Toyoshima, Atsushi

AU - Li, Zijie

AU - Asai, Masato

AU - Sato, Nozomi

AU - Sato, Tetsuya K.

AU - Kikuchi, Takahiro

AU - Kaneya, Yusuke

AU - Kitatsuji, Yoshihiro

AU - Tsukada, Kazuaki

AU - Nagame, Yuichiro

AU - Schädel, Matthias

AU - Ooe, Kazuhiro

AU - Kasamatsu, Yoshitaka

AU - Shinohara, Atsushi

AU - Haba, Hiromitsu

AU - Even, Julia

PY - 2013/11/4

Y1 - 2013/11/4

N2 - The reduction behavior of mendelevium (Md) was studied using a flow electrolytic chromatography apparatus. By application of the appropriate potentials on the chromatography column, the more stable Md3+ is reduced to Md2+. The reduction potential of the Md3+ + e- → Md2+ couple was determined to be -0.16 ± 0.05 V versus a normal hydrogen electrode.

AB - The reduction behavior of mendelevium (Md) was studied using a flow electrolytic chromatography apparatus. By application of the appropriate potentials on the chromatography column, the more stable Md3+ is reduced to Md2+. The reduction potential of the Md3+ + e- → Md2+ couple was determined to be -0.16 ± 0.05 V versus a normal hydrogen electrode.

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U2 - 10.1021/ic401571h

DO - 10.1021/ic401571h

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JO - Inorganic chemistry

JF - Inorganic chemistry

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ER -

Measurement of the Md³⁺/Md²⁺ reduction potential studied with flow electrolytic chromatography

Abstract

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