MALDI TOF mass study on oligomerization of Pd(OAc)2(L) 2 (L = Pyridine derivatives): Relevance to Pd black formation in Pd-catalyzed air oxidation of alcohols

Tomoko Komano; Tetsuo Iwasawa; Makoto Tokunaga; Yasushi Obora; Yasushi Tsuji

doi:10.1021/ol051845o

MALDI TOF mass study on oligomerization of Pd(OAc)₂(L) ₂ (L = Pyridine derivatives): Relevance to Pd black formation in Pd-catalyzed air oxidation of alcohols

Tomoko Komano, Tetsuo Iwasawa, Makoto Tokunaga, Yasushi Obora, Yasushi Tsuji

Research output: Contribution to journal › Article › peer-review

24 Citations (Scopus)

Abstract

(Chemical Equation Presented) Oligomerization of Pd(OAc) ₂(L)₂ (L = pyridine derivatives), a catalyst for the air oxidation of alcohols, is studied with MALDI TOF mass, using dithranol as the matrix. The degree of the Pd oligomerization is influenced by the pyridine ligands, and this ligand effect is similar to one observed for Pd black formation in the catalysis.

Original language	English
Pages (from-to)	4677-4679
Number of pages	3
Journal	Organic letters
Volume	7
Issue number	21
DOIs	https://doi.org/10.1021/ol051845o
Publication status	Published - Oct 13 2005
Externally published	Yes

All Science Journal Classification (ASJC) codes

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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10.1021/ol051845o

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abstract = "(Chemical Equation Presented) Oligomerization of Pd(OAc) 2(L)2 (L = pyridine derivatives), a catalyst for the air oxidation of alcohols, is studied with MALDI TOF mass, using dithranol as the matrix. The degree of the Pd oligomerization is influenced by the pyridine ligands, and this ligand effect is similar to one observed for Pd black formation in the catalysis.",

author = "Tomoko Komano and Tetsuo Iwasawa and Makoto Tokunaga and Yasushi Obora and Yasushi Tsuji",

year = "2005",

month = oct,

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doi = "10.1021/ol051845o",

language = "English",

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journal = "Organic letters",

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T1 - MALDI TOF mass study on oligomerization of Pd(OAc)2(L) 2 (L = Pyridine derivatives)

T2 - Relevance to Pd black formation in Pd-catalyzed air oxidation of alcohols

AU - Komano, Tomoko

AU - Iwasawa, Tetsuo

AU - Tokunaga, Makoto

AU - Obora, Yasushi

AU - Tsuji, Yasushi

PY - 2005/10/13

Y1 - 2005/10/13

N2 - (Chemical Equation Presented) Oligomerization of Pd(OAc) 2(L)2 (L = pyridine derivatives), a catalyst for the air oxidation of alcohols, is studied with MALDI TOF mass, using dithranol as the matrix. The degree of the Pd oligomerization is influenced by the pyridine ligands, and this ligand effect is similar to one observed for Pd black formation in the catalysis.

AB - (Chemical Equation Presented) Oligomerization of Pd(OAc) 2(L)2 (L = pyridine derivatives), a catalyst for the air oxidation of alcohols, is studied with MALDI TOF mass, using dithranol as the matrix. The degree of the Pd oligomerization is influenced by the pyridine ligands, and this ligand effect is similar to one observed for Pd black formation in the catalysis.

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DO - 10.1021/ol051845o

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SP - 4677

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JO - Organic letters

JF - Organic letters

IS - 21

ER -

MALDI TOF mass study on oligomerization of Pd(OAc)₂(L) ₂ (L = Pyridine derivatives): Relevance to Pd black formation in Pd-catalyzed air oxidation of alcohols

Abstract

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