Luminescent ionic liquid formed from a melted rhenium(v) cluster

Junichi Yanagisawa; Tomoaki Hiraoka; Fumiya Kobayashi; Daisuke Saito; Masaki Yoshida; Masako Kato; Fumitaka Takeiri; Genki Kobayashi; Masaaki Ohba; Leonard F. Lindoy; Ryo Ohtani; Shinya Hayami

doi:10.1039/d0cc02937h

Luminescent ionic liquid formed from a melted rhenium(v) cluster

Junichi Yanagisawa, Tomoaki Hiraoka, Fumiya Kobayashi, Daisuke Saito, Masaki Yoshida, Masako Kato, Fumitaka Takeiri, Genki Kobayashi, Masaaki Ohba, Leonard F. Lindoy, Ryo Ohtani, Shinya Hayami

Inorganic and Analytical Chemistry

Research output: Contribution to journal › Article › peer-review

12 Citations (Scopus)

Abstract

Recently, non-crystalline coordination materials have been shown to represent a versatile class of functional materials. However, such materials incorporating metal complex clusters have remained largely unexplored. Herein, we demonstrate that a luminescent tetranuclear ReV cluster melts at 489 K, with the cluster structure being maintained in the corresponding supercooled ionic liquid phase.

Original language	English
Pages (from-to)	7957-7960
Number of pages	4
Journal	Chemical communications (Cambridge, England)
Volume	56
Issue number	57
DOIs	https://doi.org/10.1039/d0cc02937h
Publication status	Published - Jul 17 2020

All Science Journal Classification (ASJC) codes

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

Access to Document

10.1039/d0cc02937h

Cite this

@article{b6062cbbbbf94c0eb86892b53d6c223d,

title = "Luminescent ionic liquid formed from a melted rhenium(v) cluster",

abstract = "Recently, non-crystalline coordination materials have been shown to represent a versatile class of functional materials. However, such materials incorporating metal complex clusters have remained largely unexplored. Herein, we demonstrate that a luminescent tetranuclear ReV cluster melts at 489 K, with the cluster structure being maintained in the corresponding supercooled ionic liquid phase.",

author = "Junichi Yanagisawa and Tomoaki Hiraoka and Fumiya Kobayashi and Daisuke Saito and Masaki Yoshida and Masako Kato and Fumitaka Takeiri and Genki Kobayashi and Masaaki Ohba and Lindoy, {Leonard F.} and Ryo Ohtani and Shinya Hayami",

year = "2020",

month = jul,

day = "17",

doi = "10.1039/d0cc02937h",

language = "English",

volume = "56",

pages = "7957--7960",

journal = "Chemical communications (Cambridge, England)",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "57",

}

TY - JOUR

T1 - Luminescent ionic liquid formed from a melted rhenium(v) cluster

AU - Yanagisawa, Junichi

AU - Hiraoka, Tomoaki

AU - Kobayashi, Fumiya

AU - Saito, Daisuke

AU - Yoshida, Masaki

AU - Kato, Masako

AU - Takeiri, Fumitaka

AU - Kobayashi, Genki

AU - Ohba, Masaaki

AU - Lindoy, Leonard F.

AU - Ohtani, Ryo

AU - Hayami, Shinya

PY - 2020/7/17

Y1 - 2020/7/17

N2 - Recently, non-crystalline coordination materials have been shown to represent a versatile class of functional materials. However, such materials incorporating metal complex clusters have remained largely unexplored. Herein, we demonstrate that a luminescent tetranuclear ReV cluster melts at 489 K, with the cluster structure being maintained in the corresponding supercooled ionic liquid phase.

AB - Recently, non-crystalline coordination materials have been shown to represent a versatile class of functional materials. However, such materials incorporating metal complex clusters have remained largely unexplored. Herein, we demonstrate that a luminescent tetranuclear ReV cluster melts at 489 K, with the cluster structure being maintained in the corresponding supercooled ionic liquid phase.

UR - http://www.scopus.com/inward/record.url?scp=85088496183&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85088496183&partnerID=8YFLogxK

U2 - 10.1039/d0cc02937h

DO - 10.1039/d0cc02937h

M3 - Article

C2 - 32537623

AN - SCOPUS:85088496183

SN - 1359-7345

VL - 56

SP - 7957

EP - 7960

JO - Chemical communications (Cambridge, England)

JF - Chemical communications (Cambridge, England)

IS - 57

ER -

Luminescent ionic liquid formed from a melted rhenium(v) cluster

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this