Low melting and electrochemically stable ionic liquids based on asymmetric fluorosulfonyl(trifluoromethylsulfonyl)amide

Hajime Matsumoto; Naohiro Terasawa; Tatsuya Umecky; Seiji Tsuzuki; Hikari Sakaebe; Kinji Asaka; Kuniaki Tatsumi

doi:10.1246/cl.2008.1020

Low melting and electrochemically stable ionic liquids based on asymmetric fluorosulfonyl(trifluoromethylsulfonyl)amide

Hajime Matsumoto
, Naohiro Terasawa
, Tatsuya Umecky
, Seiji Tsuzuki
, Hikari Sakaebe
, Kinji Asaka
, Kuniaki Tatsumi

Research output: Contribution to journal › Article › peer-review

67 Citations (Scopus)

Abstract

An asymmetric amide anion, FTA ^- ([(FSO ₂XCF ₃SO ₂)N] ^-}, has a significant ability to reduce the melting points of an aliphatic quaternary ammonium salts even for a symmetric tetraethylammonium. Much more interestingly, the electrochemical stability of this anion was comparable to a typical amide anion, such as bis(trifluoromethylsulfonyl)amide.

Original language	English
Pages (from-to)	1020-1021
Number of pages	2
Journal	Chemistry Letters
Volume	37
Issue number	10
DOIs	https://doi.org/10.1246/cl.2008.1020
Publication status	Published - 2008
Externally published	Yes

All Science Journal Classification (ASJC) codes

General Chemistry

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10.1246/cl.2008.1020

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title = "Low melting and electrochemically stable ionic liquids based on asymmetric fluorosulfonyl(trifluoromethylsulfonyl)amide",

abstract = "An asymmetric amide anion, FTA - ([(FSO 2XCF 3SO 2)N] -\}, has a significant ability to reduce the melting points of an aliphatic quaternary ammonium salts even for a symmetric tetraethylammonium. Much more interestingly, the electrochemical stability of this anion was comparable to a typical amide anion, such as bis(trifluoromethylsulfonyl)amide.",

author = "Hajime Matsumoto and Naohiro Terasawa and Tatsuya Umecky and Seiji Tsuzuki and Hikari Sakaebe and Kinji Asaka and Kuniaki Tatsumi",

year = "2008",

doi = "10.1246/cl.2008.1020",

language = "English",

volume = "37",

pages = "1020--1021",

journal = "Chemistry Letters",

issn = "0366-7022",

publisher = "Oxford University Press",

number = "10",

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T1 - Low melting and electrochemically stable ionic liquids based on asymmetric fluorosulfonyl(trifluoromethylsulfonyl)amide

AU - Matsumoto, Hajime

AU - Terasawa, Naohiro

AU - Umecky, Tatsuya

AU - Tsuzuki, Seiji

AU - Sakaebe, Hikari

AU - Asaka, Kinji

AU - Tatsumi, Kuniaki

PY - 2008

Y1 - 2008

N2 - An asymmetric amide anion, FTA - ([(FSO 2XCF 3SO 2)N] -}, has a significant ability to reduce the melting points of an aliphatic quaternary ammonium salts even for a symmetric tetraethylammonium. Much more interestingly, the electrochemical stability of this anion was comparable to a typical amide anion, such as bis(trifluoromethylsulfonyl)amide.

AB - An asymmetric amide anion, FTA - ([(FSO 2XCF 3SO 2)N] -}, has a significant ability to reduce the melting points of an aliphatic quaternary ammonium salts even for a symmetric tetraethylammonium. Much more interestingly, the electrochemical stability of this anion was comparable to a typical amide anion, such as bis(trifluoromethylsulfonyl)amide.

UR - https://www.scopus.com/pages/publications/67649186393

UR - https://www.scopus.com/pages/publications/67649186393#tab=citedBy

U2 - 10.1246/cl.2008.1020

DO - 10.1246/cl.2008.1020

M3 - Article

AN - SCOPUS:67649186393

SN - 0366-7022

VL - 37

SP - 1020

EP - 1021

JO - Chemistry Letters

JF - Chemistry Letters

IS - 10

ER -

Low melting and electrochemically stable ionic liquids based on asymmetric fluorosulfonyl(trifluoromethylsulfonyl)amide

Abstract

All Science Journal Classification (ASJC) codes

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