Li+/Na+ exchange from α-NaFeO2 using hydrothermal reaction

Mitsuharu Tabuchi; Christian Masquelier; Tomonari Takeuchi; Kazuaki Ado; Ichiro Matsubara; Takayuki Shirane; Ryoji Kanno; Satoshi Tsutsui; Saburo Nasu; Hikari Sakaebe; Osamu Nakamura

doi:10.1016/s0167-2738(96)00414-6

Li⁺/Na⁺ exchange from α-NaFeO₂ using hydrothermal reaction

Mitsuharu Tabuchi, Christian Masquelier, Tomonari Takeuchi, Kazuaki Ado, Ichiro Matsubara, Takayuki Shirane, Ryoji Kanno, Satoshi Tsutsui, Saburo Nasu, Hikari Sakaebe, Osamu Nakamura

Research output: Contribution to journal › Article › peer-review

42 Citations (Scopus)

Abstract

A Li⁺/Na⁺ exchange reaction was performed at 140°C under hydrothermal conditions to react α-NaFeO₂ (also prepared hydrothermally) with a large excess of LiOH · H₂O, either in methanol or in ethanol, used as solvents. Each of the XRD peaks obtained from the hydrothermally ion-exchanged sample are indexable using the rhombohedral (hexagonal) unit cell of layered-LiFeO₂. The chemical composition of the sample is estimated to be Li_0.8Na_0.2FeO₂. The magnetic properties of Li_0.8Na_0.2FeO₂ are quite similar with layered-LiFeO₂, rather than those of α-LiFeO₂.

Original language	English
Pages (from-to)	129-132
Number of pages	4
Journal	Solid State Ionics
Volume	90
Issue number	1-4
DOIs	https://doi.org/10.1016/s0167-2738(96)00414-6
Publication status	Published - Sept 1996
Externally published	Yes

All Science Journal Classification (ASJC) codes

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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10.1016/s0167-2738(96)00414-6

Cite this

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title = "Li+/Na+ exchange from α-NaFeO2 using hydrothermal reaction",

abstract = "A Li+/Na+ exchange reaction was performed at 140°C under hydrothermal conditions to react α-NaFeO2 (also prepared hydrothermally) with a large excess of LiOH · H2O, either in methanol or in ethanol, used as solvents. Each of the XRD peaks obtained from the hydrothermally ion-exchanged sample are indexable using the rhombohedral (hexagonal) unit cell of layered-LiFeO2. The chemical composition of the sample is estimated to be Li0.8Na0.2FeO2. The magnetic properties of Li0.8Na0.2FeO2 are quite similar with layered-LiFeO2, rather than those of α-LiFeO2.",

author = "Mitsuharu Tabuchi and Christian Masquelier and Tomonari Takeuchi and Kazuaki Ado and Ichiro Matsubara and Takayuki Shirane and Ryoji Kanno and Satoshi Tsutsui and Saburo Nasu and Hikari Sakaebe and Osamu Nakamura",

year = "1996",

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doi = "10.1016/s0167-2738(96)00414-6",

language = "English",

volume = "90",

pages = "129--132",

journal = "Solid State Ionics",

issn = "0167-2738",

publisher = "Elsevier",

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TY - JOUR

T1 - Li+/Na+ exchange from α-NaFeO2 using hydrothermal reaction

AU - Tabuchi, Mitsuharu

AU - Masquelier, Christian

AU - Takeuchi, Tomonari

AU - Ado, Kazuaki

AU - Matsubara, Ichiro

AU - Shirane, Takayuki

AU - Kanno, Ryoji

AU - Tsutsui, Satoshi

AU - Nasu, Saburo

AU - Sakaebe, Hikari

AU - Nakamura, Osamu

PY - 1996/9

Y1 - 1996/9

N2 - A Li+/Na+ exchange reaction was performed at 140°C under hydrothermal conditions to react α-NaFeO2 (also prepared hydrothermally) with a large excess of LiOH · H2O, either in methanol or in ethanol, used as solvents. Each of the XRD peaks obtained from the hydrothermally ion-exchanged sample are indexable using the rhombohedral (hexagonal) unit cell of layered-LiFeO2. The chemical composition of the sample is estimated to be Li0.8Na0.2FeO2. The magnetic properties of Li0.8Na0.2FeO2 are quite similar with layered-LiFeO2, rather than those of α-LiFeO2.

AB - A Li+/Na+ exchange reaction was performed at 140°C under hydrothermal conditions to react α-NaFeO2 (also prepared hydrothermally) with a large excess of LiOH · H2O, either in methanol or in ethanol, used as solvents. Each of the XRD peaks obtained from the hydrothermally ion-exchanged sample are indexable using the rhombohedral (hexagonal) unit cell of layered-LiFeO2. The chemical composition of the sample is estimated to be Li0.8Na0.2FeO2. The magnetic properties of Li0.8Na0.2FeO2 are quite similar with layered-LiFeO2, rather than those of α-LiFeO2.

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DO - 10.1016/s0167-2738(96)00414-6

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SN - 0167-2738

VL - 90

SP - 129

EP - 132

JO - Solid State Ionics

JF - Solid State Ionics

IS - 1-4

ER -

Li⁺/Na⁺ exchange from α-NaFeO₂ using hydrothermal reaction

Abstract

All Science Journal Classification (ASJC) codes

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