Large reverse saturable absorption under weak continuous incoherent light

Shuzo Hirata, Kenro Totani, Takashi Yamashita, Chihaya Adachi, Martin Vacha

Research output: Contribution to journalArticlepeer-review

120 Citations (Scopus)


In materials showing reverse saturable absorption (RSA), the optical absorbance increases as the power of the light incident on them increases. To date, RSA has only been observed when very intense light sources, such as short-pulse lasers, are used. Here, we show that hydroxyl steroidal matrices embedding properly designed aromatic molecules as acceptors and transition-metal complexes as donors exhibit high RSA on exposure to weak incoherent light at room temperature and in air. Accumulation by photosensitization of long-lived roomerature triplet excitons in acceptors with a large triplet-triplet absorption coefficient allows a nonlinear increase in absorbance also under low-power irradiation conditions. As a consequence, continuous exposure to weak light significantly decreases the transmittance of thin films fabricated with these compounds. These optical limiting properties may be used to protect eyes and light sensors from exposure to intense radiation generated by incoherent sources and for other light-absorption applications that have not been realized with conventional RSA materials.

Original languageEnglish
Pages (from-to)938-946
Number of pages9
JournalNature Materials
Issue number10
Publication statusPublished - Oct 1 2014

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering


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