Lanthanoid triflates catalyzed reaction of a silyl ynolate with aldimines

Mitsuru Shindo; Soichiro Oya; Yusuke Sato; Kozo Shishido

doi:10.3987/COM-99-S70

Lanthanoid triflates catalyzed reaction of a silyl ynolate with aldimines

Mitsuru Shindo, Soichiro Oya, Yusuke Sato, Kozo Shishido

Research output: Contribution to journal › Article › peer-review

27 Citations (Scopus)

Abstract

A silyl ynolate, prepared from α,α-dibromo ester in one-pot, reacts with N-(p-methoxyphenyl)aldimines in the presence of a catalytic amount of lanthanoid triflates to provide α,β-unsaturated amides with high E selectivity.

Original language	English
Pages (from-to)	545-548
Number of pages	4
Journal	Heterocycles
Volume	52
Issue number	2
DOIs	https://doi.org/10.3987/COM-99-S70
Publication status	Published - Feb 1 2000
Externally published	Yes

All Science Journal Classification (ASJC) codes

Analytical Chemistry
Pharmacology
Organic Chemistry

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10.3987/COM-99-S70

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title = "Lanthanoid triflates catalyzed reaction of a silyl ynolate with aldimines",

abstract = "A silyl ynolate, prepared from α,α-dibromo ester in one-pot, reacts with N-(p-methoxyphenyl)aldimines in the presence of a catalytic amount of lanthanoid triflates to provide α,β-unsaturated amides with high E selectivity.",

author = "Mitsuru Shindo and Soichiro Oya and Yusuke Sato and Kozo Shishido",

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AU - Shindo, Mitsuru

AU - Oya, Soichiro

AU - Sato, Yusuke

AU - Shishido, Kozo

PY - 2000/2/1

Y1 - 2000/2/1

N2 - A silyl ynolate, prepared from α,α-dibromo ester in one-pot, reacts with N-(p-methoxyphenyl)aldimines in the presence of a catalytic amount of lanthanoid triflates to provide α,β-unsaturated amides with high E selectivity.

AB - A silyl ynolate, prepared from α,α-dibromo ester in one-pot, reacts with N-(p-methoxyphenyl)aldimines in the presence of a catalytic amount of lanthanoid triflates to provide α,β-unsaturated amides with high E selectivity.

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JO - Heterocycles

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Lanthanoid triflates catalyzed reaction of a silyl ynolate with aldimines

Abstract

All Science Journal Classification (ASJC) codes

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