Isomerization of an axial ligand coordinated to hydrophobic vitamin B12 as effected by cyanide ion and microenvironment

Teruhisa Ohno; Akihiro Ogawa; Yoshio Hisaeda; Yukito Murakami

doi:10.1016/0040-4039(94)88518-4

Isomerization of an axial ligand coordinated to hydrophobic vitamin B₁₂ as effected by cyanide ion and microenvironment

Teruhisa Ohno, Akihiro Ogawa, Yoshio Hisaeda, Yukito Murakami

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

The cyanide ion enhanced a carbon-skeleton rearrangement of the 2,3-bis(ethoxycarbonyl)-1-butene moiety bound to hydrophobic vitamin B₁₂ derivatives in single-compartment bilayer vesicles under photolysis conditions via formation of the anionic substrate intermediate.

Original language	English
Pages (from-to)	9589-9592
Number of pages	4
Journal	Tetrahedron Letters
Volume	35
Issue number	51
DOIs	https://doi.org/10.1016/0040-4039(94)88518-4
Publication status	Published - Dec 19 1994

All Science Journal Classification (ASJC) codes

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/0040-4039(94)88518-4

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title = "Isomerization of an axial ligand coordinated to hydrophobic vitamin B12 as effected by cyanide ion and microenvironment",

abstract = "The cyanide ion enhanced a carbon-skeleton rearrangement of the 2,3-bis(ethoxycarbonyl)-1-butene moiety bound to hydrophobic vitamin B12 derivatives in single-compartment bilayer vesicles under photolysis conditions via formation of the anionic substrate intermediate.",

author = "Teruhisa Ohno and Akihiro Ogawa and Yoshio Hisaeda and Yukito Murakami",

year = "1994",

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doi = "10.1016/0040-4039(94)88518-4",

language = "English",

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T1 - Isomerization of an axial ligand coordinated to hydrophobic vitamin B12 as effected by cyanide ion and microenvironment

AU - Ohno, Teruhisa

AU - Ogawa, Akihiro

AU - Hisaeda, Yoshio

AU - Murakami, Yukito

PY - 1994/12/19

Y1 - 1994/12/19

N2 - The cyanide ion enhanced a carbon-skeleton rearrangement of the 2,3-bis(ethoxycarbonyl)-1-butene moiety bound to hydrophobic vitamin B12 derivatives in single-compartment bilayer vesicles under photolysis conditions via formation of the anionic substrate intermediate.

AB - The cyanide ion enhanced a carbon-skeleton rearrangement of the 2,3-bis(ethoxycarbonyl)-1-butene moiety bound to hydrophobic vitamin B12 derivatives in single-compartment bilayer vesicles under photolysis conditions via formation of the anionic substrate intermediate.

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U2 - 10.1016/0040-4039(94)88518-4

DO - 10.1016/0040-4039(94)88518-4

M3 - Article

AN - SCOPUS:0028148641

SN - 0040-4039

VL - 35

SP - 9589

EP - 9592

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 51

ER -

Isomerization of an axial ligand coordinated to hydrophobic vitamin B₁₂ as effected by cyanide ion and microenvironment

Abstract

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