Isolation of a MnIV acylperoxo complex and its monooxidation ability

Takahiro Kikunaga; Takahiro Matsumoto; Takehiro Ohta; Hidetaka Nakai; Yoshinori Naruta; Kwang Hyun Ahn; Yoshihito Watanabe; Seiji Ogo

doi:10.1039/c3cc43447h

Isolation of a Mn^IV acylperoxo complex and its monooxidation ability

Takahiro Kikunaga, Takahiro Matsumoto, Takehiro Ohta, Hidetaka Nakai, Yoshinori Naruta, Kwang Hyun Ahn, Yoshihito Watanabe, Seiji Ogo

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

The first example of monooxygenation by a high-valent Mn^IV complex with a peroxide is described. A key Mn^IV acylperoxo intermediate, which uses m-chloroperoxybenzoic acid as the oxygen donor, is directly observed by electro-spray ionization mass spectrometry and resonance Raman spectroscopy.

Original language	English
Pages (from-to)	8356-8358
Number of pages	3
Journal	Chemical Communications
Volume	49
Issue number	75
DOIs	https://doi.org/10.1039/c3cc43447h
Publication status	Published - Aug 22 2013

All Science Journal Classification (ASJC) codes

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

Access to Document

10.1039/c3cc43447h

Cite this

@article{6f5553fc522c496898cc072470beae17,

title = "Isolation of a MnIV acylperoxo complex and its monooxidation ability",

abstract = "The first example of monooxygenation by a high-valent MnIV complex with a peroxide is described. A key MnIV acylperoxo intermediate, which uses m-chloroperoxybenzoic acid as the oxygen donor, is directly observed by electro-spray ionization mass spectrometry and resonance Raman spectroscopy.",

author = "Takahiro Kikunaga and Takahiro Matsumoto and Takehiro Ohta and Hidetaka Nakai and Yoshinori Naruta and Ahn, {Kwang Hyun} and Yoshihito Watanabe and Seiji Ogo",

year = "2013",

month = aug,

day = "22",

doi = "10.1039/c3cc43447h",

language = "English",

volume = "49",

pages = "8356--8358",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "75",

}

TY - JOUR

T1 - Isolation of a MnIV acylperoxo complex and its monooxidation ability

AU - Kikunaga, Takahiro

AU - Matsumoto, Takahiro

AU - Ohta, Takehiro

AU - Nakai, Hidetaka

AU - Naruta, Yoshinori

AU - Ahn, Kwang Hyun

AU - Watanabe, Yoshihito

AU - Ogo, Seiji

PY - 2013/8/22

Y1 - 2013/8/22

N2 - The first example of monooxygenation by a high-valent MnIV complex with a peroxide is described. A key MnIV acylperoxo intermediate, which uses m-chloroperoxybenzoic acid as the oxygen donor, is directly observed by electro-spray ionization mass spectrometry and resonance Raman spectroscopy.

AB - The first example of monooxygenation by a high-valent MnIV complex with a peroxide is described. A key MnIV acylperoxo intermediate, which uses m-chloroperoxybenzoic acid as the oxygen donor, is directly observed by electro-spray ionization mass spectrometry and resonance Raman spectroscopy.

UR - http://www.scopus.com/inward/record.url?scp=84883210165&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84883210165&partnerID=8YFLogxK

U2 - 10.1039/c3cc43447h

DO - 10.1039/c3cc43447h

M3 - Article

C2 - 23929258

AN - SCOPUS:84883210165

SN - 1359-7345

VL - 49

SP - 8356

EP - 8358

JO - Chemical Communications

JF - Chemical Communications

IS - 75

ER -

Isolation of a Mn^IV acylperoxo complex and its monooxidation ability

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this