Iron promoted conjugate addition: Implication of the six-centered mechanism based on the isolation of the iron-enolate intermediate

Daisuke Noda; Yusuke Sunada; Takuji Hatakeyama; Masaharu Nakamura; Hideo Nagashima

doi:10.1039/c2cc37144h

Iron promoted conjugate addition: Implication of the six-centered mechanism based on the isolation of the iron-enolate intermediate

Daisuke Noda, Yusuke Sunada, Takuji Hatakeyama, Masaharu Nakamura, Hideo Nagashima

Department of Applied Molecular Chemistry

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

Treatment of (η¹-mesityl)₂Fe(κ²-TMEDA) (1’) with an α,β-unsaturated carbonyl compound results in 1,4-addition of the mesityl group to give an iron enolate 3 quantitatively. The Z-configuration of the enolate suggested the six-centered mechanism for the conjugate addition.

Original language	English
Pages (from-to)	12231-12233
Number of pages	3
Journal	Chemical Communications
Volume	48
Issue number	100
DOIs	https://doi.org/10.1039/c2cc37144h
Publication status	Published - Nov 21 2012

All Science Journal Classification (ASJC) codes

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

Access to Document

10.1039/c2cc37144h

Cite this

@article{8012e2b242b646aea0c732613f320a95,

title = "Iron promoted conjugate addition: Implication of the six-centered mechanism based on the isolation of the iron-enolate intermediate",

abstract = "Treatment of (η1-mesityl)2Fe(κ2-TMEDA) (1{\textquoteright}) with an α,β-unsaturated carbonyl compound results in 1,4-addition of the mesityl group to give an iron enolate 3 quantitatively. The Z-configuration of the enolate suggested the six-centered mechanism for the conjugate addition.",

author = "Daisuke Noda and Yusuke Sunada and Takuji Hatakeyama and Masaharu Nakamura and Hideo Nagashima",

year = "2012",

month = nov,

day = "21",

doi = "10.1039/c2cc37144h",

language = "English",

volume = "48",

pages = "12231--12233",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "100",

}

TY - JOUR

T1 - Iron promoted conjugate addition

T2 - Implication of the six-centered mechanism based on the isolation of the iron-enolate intermediate

AU - Noda, Daisuke

AU - Sunada, Yusuke

AU - Hatakeyama, Takuji

AU - Nakamura, Masaharu

AU - Nagashima, Hideo

PY - 2012/11/21

Y1 - 2012/11/21

N2 - Treatment of (η1-mesityl)2Fe(κ2-TMEDA) (1’) with an α,β-unsaturated carbonyl compound results in 1,4-addition of the mesityl group to give an iron enolate 3 quantitatively. The Z-configuration of the enolate suggested the six-centered mechanism for the conjugate addition.

AB - Treatment of (η1-mesityl)2Fe(κ2-TMEDA) (1’) with an α,β-unsaturated carbonyl compound results in 1,4-addition of the mesityl group to give an iron enolate 3 quantitatively. The Z-configuration of the enolate suggested the six-centered mechanism for the conjugate addition.

UR - http://www.scopus.com/inward/record.url?scp=84869996123&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84869996123&partnerID=8YFLogxK

U2 - 10.1039/c2cc37144h

DO - 10.1039/c2cc37144h

M3 - Article

C2 - 23147813

AN - SCOPUS:84869996123

SN - 1359-7345

VL - 48

SP - 12231

EP - 12233

JO - Chemical Communications

JF - Chemical Communications

IS - 100

ER -

Iron promoted conjugate addition: Implication of the six-centered mechanism based on the isolation of the iron-enolate intermediate

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this