Iron-catalyzed synthesis of glycine derivatives via carbon-nitrogen bond cleavage using diazoacetate

Yoichiro Kuninobu; Mitsumi Nishi; Kazuhiko Takai

doi:10.1039/c0cc03781h

Iron-catalyzed synthesis of glycine derivatives via carbon-nitrogen bond cleavage using diazoacetate

Yoichiro Kuninobu, Mitsumi Nishi, Kazuhiko Takai

Research output: Contribution to journal › Article › peer-review

45 Citations (Scopus)

Abstract

Treatment of tertiary amines with diazoacetate in the presence of a catalytic amount of an iron salt, FeCl₃, in ethanol gave glycine derivatives. In this reaction, a carbon-nitrogen single bond of the amine was cleaved.

Original language	English
Pages (from-to)	8860-8862
Number of pages	3
Journal	Chemical Communications
Volume	46
Issue number	46
DOIs	https://doi.org/10.1039/c0cc03781h
Publication status	Published - Dec 14 2010
Externally published	Yes

All Science Journal Classification (ASJC) codes

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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title = "Iron-catalyzed synthesis of glycine derivatives via carbon-nitrogen bond cleavage using diazoacetate",

abstract = "Treatment of tertiary amines with diazoacetate in the presence of a catalytic amount of an iron salt, FeCl3, in ethanol gave glycine derivatives. In this reaction, a carbon-nitrogen single bond of the amine was cleaved.",

author = "Yoichiro Kuninobu and Mitsumi Nishi and Kazuhiko Takai",

year = "2010",

month = dec,

day = "14",

doi = "10.1039/c0cc03781h",

language = "English",

volume = "46",

pages = "8860--8862",

journal = "Chemical Communications",

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T1 - Iron-catalyzed synthesis of glycine derivatives via carbon-nitrogen bond cleavage using diazoacetate

AU - Kuninobu, Yoichiro

AU - Nishi, Mitsumi

AU - Takai, Kazuhiko

PY - 2010/12/14

Y1 - 2010/12/14

N2 - Treatment of tertiary amines with diazoacetate in the presence of a catalytic amount of an iron salt, FeCl3, in ethanol gave glycine derivatives. In this reaction, a carbon-nitrogen single bond of the amine was cleaved.

AB - Treatment of tertiary amines with diazoacetate in the presence of a catalytic amount of an iron salt, FeCl3, in ethanol gave glycine derivatives. In this reaction, a carbon-nitrogen single bond of the amine was cleaved.

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U2 - 10.1039/c0cc03781h

DO - 10.1039/c0cc03781h

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SN - 1359-7345

VL - 46

SP - 8860

EP - 8862

JO - Chemical Communications

JF - Chemical Communications

IS - 46

ER -

Iron-catalyzed synthesis of glycine derivatives via carbon-nitrogen bond cleavage using diazoacetate

Abstract

All Science Journal Classification (ASJC) codes

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