Iridium-catalysed borylation of sterically hindered C(sp3)-H bonds: Remarkable rate acceleration by a catalytic amount of potassium tert-butoxide

Toshimichi Ohmura; Takeru Torigoe; Michinori Suginome

doi:10.1039/c4cc01262c

Iridium-catalysed borylation of sterically hindered C(sp³)-H bonds: Remarkable rate acceleration by a catalytic amount of potassium tert-butoxide

Toshimichi Ohmura, Takeru Torigoe, Michinori Suginome

Research output: Contribution to journal › Article › peer-review

38 Citations (Scopus)

Abstract

The C(sp³)-H bonds located on the methyl groups of an isopropyl group participate in iridium-catalysed C-H borylation with bis(pinacolato)diboron via a significant rate acceleration caused by a catalytic amount of t-BuOK.

Original language	English
Pages (from-to)	6333-6336
Number of pages	4
Journal	Chemical Communications
Volume	50
Issue number	48
DOIs	https://doi.org/10.1039/c4cc01262c
Publication status	Published - May 20 2014
Externally published	Yes

All Science Journal Classification (ASJC) codes

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/c4cc01262c

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title = "Iridium-catalysed borylation of sterically hindered C(sp3)-H bonds: Remarkable rate acceleration by a catalytic amount of potassium tert-butoxide",

abstract = "The C(sp3)-H bonds located on the methyl groups of an isopropyl group participate in iridium-catalysed C-H borylation with bis(pinacolato)diboron via a significant rate acceleration caused by a catalytic amount of t-BuOK.",

author = "Toshimichi Ohmura and Takeru Torigoe and Michinori Suginome",

year = "2014",

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doi = "10.1039/c4cc01262c",

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publisher = "Royal Society of Chemistry",

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AU - Torigoe, Takeru

AU - Suginome, Michinori

PY - 2014/5/20

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AB - The C(sp3)-H bonds located on the methyl groups of an isopropyl group participate in iridium-catalysed C-H borylation with bis(pinacolato)diboron via a significant rate acceleration caused by a catalytic amount of t-BuOK.

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DO - 10.1039/c4cc01262c

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JO - Chemical Communications

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IS - 48

ER -

Iridium-catalysed borylation of sterically hindered C(sp³)-H bonds: Remarkable rate acceleration by a catalytic amount of potassium tert-butoxide

Abstract

All Science Journal Classification (ASJC) codes

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