Ionic liquids as a novel solvent for lanthanide extraction

Kazunori Nakashima; Fukiko Kubota; Tatsuo Maruyama; Masahiro Goto

doi:10.2116/analsci.19.1097

Ionic liquids as a novel solvent for lanthanide extraction

Kazunori Nakashima, Fukiko Kubota, Tatsuo Maruyama, Masahiro Goto

Research output: Contribution to journal › Article › peer-review

249 Citations (Scopus)

Abstract

Octyl(phenyl)-N,N-diisobutylcarbamoylmethyl phosphine oxide (CMPO) dissolved in an ionic liquids, 1-butyl-3-methyl-imidazolium hexafluorophosphate, greatly enhances extractability and selectivity of lanthanide cations compared to that dissolved in conventional organic solvents; further, the recovery of lanthanides extracted into ionic liquids can be accomplished using several stripping solutions containing complexing agents. The possibility of utilizing ionic liquids as novel separation media in an industrial liquid-liquid extraction process was demonstrated.

Original language	English
Pages (from-to)	1097-1098
Number of pages	2
Journal	analytical sciences
Volume	19
Issue number	8
DOIs	https://doi.org/10.2116/analsci.19.1097
Publication status	Published - Aug 1 2003

All Science Journal Classification (ASJC) codes

Analytical Chemistry

Access to Document

10.2116/analsci.19.1097

Cite this

@article{93794d1683c84dbdaf73a0ec2d1584ba,

title = "Ionic liquids as a novel solvent for lanthanide extraction",

abstract = "Octyl(phenyl)-N,N-diisobutylcarbamoylmethyl phosphine oxide (CMPO) dissolved in an ionic liquids, 1-butyl-3-methyl-imidazolium hexafluorophosphate, greatly enhances extractability and selectivity of lanthanide cations compared to that dissolved in conventional organic solvents; further, the recovery of lanthanides extracted into ionic liquids can be accomplished using several stripping solutions containing complexing agents. The possibility of utilizing ionic liquids as novel separation media in an industrial liquid-liquid extraction process was demonstrated.",

author = "Kazunori Nakashima and Fukiko Kubota and Tatsuo Maruyama and Masahiro Goto",

year = "2003",

month = aug,

day = "1",

doi = "10.2116/analsci.19.1097",

language = "English",

volume = "19",

pages = "1097--1098",

journal = "analytical sciences",

issn = "0910-6340",

publisher = "The Japan Society for Analytical Chemistry",

number = "8",

}

TY - JOUR

T1 - Ionic liquids as a novel solvent for lanthanide extraction

AU - Nakashima, Kazunori

AU - Kubota, Fukiko

AU - Maruyama, Tatsuo

AU - Goto, Masahiro

PY - 2003/8/1

Y1 - 2003/8/1

N2 - Octyl(phenyl)-N,N-diisobutylcarbamoylmethyl phosphine oxide (CMPO) dissolved in an ionic liquids, 1-butyl-3-methyl-imidazolium hexafluorophosphate, greatly enhances extractability and selectivity of lanthanide cations compared to that dissolved in conventional organic solvents; further, the recovery of lanthanides extracted into ionic liquids can be accomplished using several stripping solutions containing complexing agents. The possibility of utilizing ionic liquids as novel separation media in an industrial liquid-liquid extraction process was demonstrated.

AB - Octyl(phenyl)-N,N-diisobutylcarbamoylmethyl phosphine oxide (CMPO) dissolved in an ionic liquids, 1-butyl-3-methyl-imidazolium hexafluorophosphate, greatly enhances extractability and selectivity of lanthanide cations compared to that dissolved in conventional organic solvents; further, the recovery of lanthanides extracted into ionic liquids can be accomplished using several stripping solutions containing complexing agents. The possibility of utilizing ionic liquids as novel separation media in an industrial liquid-liquid extraction process was demonstrated.

UR - http://www.scopus.com/inward/record.url?scp=0041864247&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0041864247&partnerID=8YFLogxK

U2 - 10.2116/analsci.19.1097

DO - 10.2116/analsci.19.1097

M3 - Article

C2 - 12945658

AN - SCOPUS:0041864247

SN - 0910-6340

VL - 19

SP - 1097

EP - 1098

JO - analytical sciences

JF - analytical sciences

IS - 8

ER -

Ionic liquids as a novel solvent for lanthanide extraction

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this