Investigation of fuel NO formation from pyrrole type nitrogen

Takuya Kuwahara; Tsuyoshi Yamamoto

doi:10.1252/kakoronbunshu.35.488

Investigation of fuel NO formation from pyrrole type nitrogen

Takuya Kuwahara, Tsuyoshi Yamamoto

Product system engineering

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

The mechanism of fuel NO formation from pyrrole type nitrogen and the effects of H₂O concentration on the reaction mechanism were examined experimentally using a flow reactor and by numerical simulation with a detailed kinetic model. It was found that when H₂O concentration is increased, the O radical is consumed and the OH radical is produced by the reaction O+→H₂O→OH+OH. Consequently, the reaction HCN+OH, the reaction by which HCN is consumed, is promoted; and the reaction NCO+O→NO+CO, the reaction by which NO is produced, is inhibited.

Original language	English
Pages (from-to)	488-494
Number of pages	7
Journal	kagaku kogaku ronbunshu
Volume	35
Issue number	5
DOIs	https://doi.org/10.1252/kakoronbunshu.35.488
Publication status	Published - Oct 2009

All Science Journal Classification (ASJC) codes

Chemistry(all)
Chemical Engineering(all)

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10.1252/kakoronbunshu.35.488

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abstract = "The mechanism of fuel NO formation from pyrrole type nitrogen and the effects of H2O concentration on the reaction mechanism were examined experimentally using a flow reactor and by numerical simulation with a detailed kinetic model. It was found that when H2O concentration is increased, the O radical is consumed and the OH radical is produced by the reaction O+→H2O→OH+OH. Consequently, the reaction HCN+OH, the reaction by which HCN is consumed, is promoted; and the reaction NCO+O→NO+CO, the reaction by which NO is produced, is inhibited.",

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AU - Yamamoto, Tsuyoshi

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AB - The mechanism of fuel NO formation from pyrrole type nitrogen and the effects of H2O concentration on the reaction mechanism were examined experimentally using a flow reactor and by numerical simulation with a detailed kinetic model. It was found that when H2O concentration is increased, the O radical is consumed and the OH radical is produced by the reaction O+→H2O→OH+OH. Consequently, the reaction HCN+OH, the reaction by which HCN is consumed, is promoted; and the reaction NCO+O→NO+CO, the reaction by which NO is produced, is inhibited.

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Investigation of fuel NO formation from pyrrole type nitrogen

Abstract

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