Inverted N-confused porphyrin dimer

Tomoya Ishizuka; Atsuhiro Osuka; Hiroyuki Furuta

doi:10.1002/anie.200460017

Inverted N-confused porphyrin dimer

Tomoya Ishizuka, Atsuhiro Osuka, Hiroyuki Furuta

Research output: Contribution to journal › Article › peer-review

51 Citations (Scopus)

Abstract

A covalently linked N-fused porphyrin dimer was synthesized by treatment of the monomer with Ag(OCOCF₃). Subsequent reaction of this dimer with NaOMe led to a porphyrin dimer with two α,β-bound ("confused") pyrrole rings (see scheme) which adopt the inverted conformation. The dimer exhibits aromaticity in spite of its highly distorted structure.

Original language	English
Pages (from-to)	5077-5081
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	43
Issue number	38
DOIs	https://doi.org/10.1002/anie.200460017
Publication status	Published - Sept 27 2004

All Science Journal Classification (ASJC) codes

Catalysis
Chemistry(all)

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10.1002/anie.200460017

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AU - Osuka, Atsuhiro

AU - Furuta, Hiroyuki

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AB - A covalently linked N-fused porphyrin dimer was synthesized by treatment of the monomer with Ag(OCOCF3). Subsequent reaction of this dimer with NaOMe led to a porphyrin dimer with two α,β-bound ("confused") pyrrole rings (see scheme) which adopt the inverted conformation. The dimer exhibits aromaticity in spite of its highly distorted structure.

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Inverted N-confused porphyrin dimer

Abstract

All Science Journal Classification (ASJC) codes

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