Intermediate-temperature, proton-conducting membranes of hafnium phosphate and zirconium phosphate/borate/sulfate

Yuanzhi Li, Emi Muto, Yoshitaka Aoki, Toyoki Kunitake

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7 Citations (Scopus)


Uniform, defect-free nanofilms (around 100 nm thick) of hafnium phosphate were prepared via layer-by-layer deposition of precursor solution of metal alkoxides and were shown to give practically useful proton conductivity at 300-400°C as fuel cell electrolyte membrane. Annealing of the deposited precursor film at 500°C gave a lower area specific resistance (R AS) than that at 400°C, and this effect was coincident with the formation of the pyrophosphate unit. The best (lowest) RAS value of less than 0.1 cm2 for hafnium phosphate membrane (annealing at 500°C, 291 nm thick, conductivity of 3 × 10-4 S cm -1 at 320°C) was comparable to that of a nanofilm of an yttrium-doped zirconium phosphate. The RAS values of nanofilms of zirconium sulfate and zirconium borate were 2-3 orders higher than that of the corresponding zirconium phosphate. It is clear from these results that nanofilms of various solid acids are promising candidates for the electrolyte membrane of fuel cells operating at the intermediate temperatures of 300-400°C.

Original languageEnglish
Pages (from-to)B1103-B1108
JournalJournal of the Electrochemical Society
Issue number8
Publication statusPublished - 2010
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Renewable Energy, Sustainability and the Environment
  • Surfaces, Coatings and Films
  • Electrochemistry
  • Materials Chemistry


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