Infrared spectroscopy of molten LiCl-KCl-LiH

Hironori Nakajima, Toshiyuki Nohira, Yasuhiko Ito

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4 Citations (Scopus)

Abstract

Infrared spectroscopy of molten LiCl-KCl-LiH at 673 K provided absorption band in the wavenumber region of 1400-1500 cm-1 for several H - ion concentrations. This absorption band is ascribed to the vibration of Li+-H- ion pair in the melt. The absorption band ascribed to the vibration of K+-H- ion pair was not observed in the melt. The existence of the Li-H interaction shows a strong attractive force between H- ion and Li+ ion in the melt.

Original languageEnglish
Pages (from-to)E27-E29
JournalElectrochemical and Solid-State Letters
Volume7
Issue number5
DOIs
Publication statusPublished - 2004
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • General Chemical Engineering
  • General Materials Science
  • Physical and Theoretical Chemistry
  • Electrochemistry
  • Electrical and Electronic Engineering

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