TY - JOUR
T1 - Influence of temperature on thermophysical properties of ammonium ionic liquids with N-methyl-2-pyrrolidone
AU - Kavitha, T.
AU - Attri, Pankaj
AU - Venkatesu, P.
AU - Rama Devi, R. S.
AU - Hofman, T.
N1 - Funding Information:
We are gratefully acknowledged the Council of Scientific Industrial Research (CSIR), New Delhi , through the Grant No. 01(2343)/09/EMR-II , Department of Science and Technology (DST), New Delhi, India (Grant No. SR/SI/PC-54/2008 ) and University Grants Commission (UGC), New Delhi for financial support.
PY - 2012/10/10
Y1 - 2012/10/10
N2 - To address the molecular interactions between ionic liquids (ILs) such as trimethylammonium acetate [(CH 3) 3NH][CH 3COO] (TMAA), trimethylammonium hydrogen sulphate [(CH 3) 3NH][HSO 4] (TMAS), trimethylammonium dihydrogen phosphate [(CH 3) 3NH][H 2PO 4] (TMAP) and triethylammonium dihydrogen phosphate [(CH 3CH 2) 3NH][H 2PO 4] (TEAP) with N-methyl-2-pyrrolidone (NMP), density (ρ), ultrasonic sound velocity (u) and viscosity (η) measurements have been performed across the entire concentration range and the wide temperature range from 298.15 to 313.15 K in steps of 5 K under ambient pressure. Further, on the basis of the measured properties, excess volumes (V E), isentropic compressibility deviations (Δκ s) and viscosity deviations (Δη) were obtained for all these systems under the same experimental conditions. The results are correlated by the Redlich-Kister type equation. The results are also analysed on anion dependent phenomena and temperature influence on measured and derived properties of ILs with NMP mixtures. A qualitative analysis of molecular interactions between ILs and NMP is discussed in terms of the ion-dipole, ion-pair interactions, and hydrogen bonding.
AB - To address the molecular interactions between ionic liquids (ILs) such as trimethylammonium acetate [(CH 3) 3NH][CH 3COO] (TMAA), trimethylammonium hydrogen sulphate [(CH 3) 3NH][HSO 4] (TMAS), trimethylammonium dihydrogen phosphate [(CH 3) 3NH][H 2PO 4] (TMAP) and triethylammonium dihydrogen phosphate [(CH 3CH 2) 3NH][H 2PO 4] (TEAP) with N-methyl-2-pyrrolidone (NMP), density (ρ), ultrasonic sound velocity (u) and viscosity (η) measurements have been performed across the entire concentration range and the wide temperature range from 298.15 to 313.15 K in steps of 5 K under ambient pressure. Further, on the basis of the measured properties, excess volumes (V E), isentropic compressibility deviations (Δκ s) and viscosity deviations (Δη) were obtained for all these systems under the same experimental conditions. The results are correlated by the Redlich-Kister type equation. The results are also analysed on anion dependent phenomena and temperature influence on measured and derived properties of ILs with NMP mixtures. A qualitative analysis of molecular interactions between ILs and NMP is discussed in terms of the ion-dipole, ion-pair interactions, and hydrogen bonding.
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U2 - 10.1016/j.tca.2012.07.004
DO - 10.1016/j.tca.2012.07.004
M3 - Article
AN - SCOPUS:84864984409
SN - 0040-6031
VL - 545
SP - 131
EP - 140
JO - Thermochimica Acta
JF - Thermochimica Acta
ER -