Importance of steric bulkiness of iridium photocatalysts with PNNP tetradentate ligands for CO2 reduction

Kenji Kamada; Jieun Jung; Yohei Kametani; Taku Wakabayashi; Yoshihito Shiota; Kazunari Yoshizawa; Seong Hee Bae; Manami Muraki; Masayuki Naruto; Keita Sekizawa; Shunsuke Sato; Takeshi Morikawa; Susumu Saito

doi:10.1039/d2cc01701f

Importance of steric bulkiness of iridium photocatalysts with PNNP tetradentate ligands for CO₂ reduction

Kenji Kamada, Jieun Jung, Yohei Kametani, Taku Wakabayashi, Yoshihito Shiota, Kazunari Yoshizawa, Seong Hee Bae, Manami Muraki, Masayuki Naruto, Keita Sekizawa, Shunsuke Sato, Takeshi Morikawa, Susumu Saito

Department of Fundamental Organic Chemistry

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

A series of Ir complexes has been developed as multifunctional photocatalysts for CO₂ reduction to give HCO₂H selectively. The catalytic activities and photophysical properties vary widely across the series, and the bulky group insertion resulted in the formation of HCO₂H and CO with the catalyst turnover number of >10 400.

Original language	English
Pages (from-to)	9218-9221
Number of pages	4
Journal	Chemical Communications
Volume	58
Issue number	66
DOIs	https://doi.org/10.1039/d2cc01701f
Publication status	Published - Jul 15 2022

All Science Journal Classification (ASJC) codes

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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title = "Importance of steric bulkiness of iridium photocatalysts with PNNP tetradentate ligands for CO2 reduction",

abstract = "A series of Ir complexes has been developed as multifunctional photocatalysts for CO2 reduction to give HCO2H selectively. The catalytic activities and photophysical properties vary widely across the series, and the bulky group insertion resulted in the formation of HCO2H and CO with the catalyst turnover number of >10 400.",

author = "Kenji Kamada and Jieun Jung and Yohei Kametani and Taku Wakabayashi and Yoshihito Shiota and Kazunari Yoshizawa and Bae, {Seong Hee} and Manami Muraki and Masayuki Naruto and Keita Sekizawa and Shunsuke Sato and Takeshi Morikawa and Susumu Saito",

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doi = "10.1039/d2cc01701f",

language = "English",

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TY - JOUR

T1 - Importance of steric bulkiness of iridium photocatalysts with PNNP tetradentate ligands for CO2 reduction

AU - Kamada, Kenji

AU - Jung, Jieun

AU - Kametani, Yohei

AU - Wakabayashi, Taku

AU - Shiota, Yoshihito

AU - Yoshizawa, Kazunari

AU - Bae, Seong Hee

AU - Muraki, Manami

AU - Naruto, Masayuki

AU - Sekizawa, Keita

AU - Sato, Shunsuke

AU - Morikawa, Takeshi

AU - Saito, Susumu

PY - 2022/7/15

Y1 - 2022/7/15

N2 - A series of Ir complexes has been developed as multifunctional photocatalysts for CO2 reduction to give HCO2H selectively. The catalytic activities and photophysical properties vary widely across the series, and the bulky group insertion resulted in the formation of HCO2H and CO with the catalyst turnover number of >10 400.

AB - A series of Ir complexes has been developed as multifunctional photocatalysts for CO2 reduction to give HCO2H selectively. The catalytic activities and photophysical properties vary widely across the series, and the bulky group insertion resulted in the formation of HCO2H and CO with the catalyst turnover number of >10 400.

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UR - http://www.scopus.com/inward/citedby.url?scp=85135229567&partnerID=8YFLogxK

U2 - 10.1039/d2cc01701f

DO - 10.1039/d2cc01701f

M3 - Article

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AN - SCOPUS:85135229567

SN - 1359-7345

VL - 58

SP - 9218

EP - 9221

JO - Chemical Communications

JF - Chemical Communications

IS - 66

ER -

Importance of steric bulkiness of iridium photocatalysts with PNNP tetradentate ligands for CO₂ reduction

Abstract

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